Studies on Synthesis and Anion Recognition of a Novel Amide Receptor Bearing Two Anthracene Substituents

Abstract

Abstract: Anovel amide anion receptor Bbearing two anthracene substituents was synthesized.The interaction between Band various anions(Cl^-, Br^-, I^-, p-O₂NC₆H₄O^-) was studied by fluorescence spectrum, UV-Vis spectruMAnd₁H NMR.The results demonstrate that Bexhibited a more significantly selective recognition for p-O₂NC₆H₄O^-than the other anions(Cl^-, Br^-, I^-Band p-O₂NC₆H₄O^-formed 1: 1 mplex.The stability constant was calculated by variation in absorbance and fluorescent emission intensity.The mechanism of the interaction between Band p-O₂NC₆H₄O^-was preliminarily studied.

Key words: Anion receptor, Synthesis, Fluorescence, Selective recognition

CLC Number:

O626

TrendMD:

ZENG Zhen-Ya, WU Jin-Long, WEI Lan-Hua, FANG Lei, HUANG Yan-Yan, MENG Ling-Zhi, HE Yong-Bing . Studies on Synthesis and Anion Recognition of a Novel Amide Receptor Bearing Two Anthracene Substituents[J]. Chem. J. Chinese Universities, 2003, 24(11): 2005.

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Studies on Synthesis and Anion Recognition of a Novel Amide Receptor Bearing Two Anthracene Substituents

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