Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (3): 399.

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Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives

ZHANG Zhao-Gui¹, HUANG Yan-Qin², ZOU Yang¹, ZHANG Shu-Kui², XIE Qing-Lan²

1. Department of Chemistry, Nanchang University, Nanchang 330047, China;
2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Received:2000-12-01 Online:2002-03-24 Published:2002-03-24

Abstract

Abstract: Seventeen tri(2-methyl-2-phenylpropyl)tinoxide derivatives were synthesized and characterized by IR, ¹H NMR and elemental analysis. Compound 7 crystallizes in the triclinic space group P1 with a=1.3944(6) nm, b=1.4846(6) nm, c=1.8028(7) nm, α=77.777(7)°, β=82.425(8)°, γ=73.581(8)°, V=3.488(2) nm³, Z=4, F(000)=1612, D_c=1.509 g/cm^-3. The ω/2θ scan technique was employed to collect data in the range of 1.16°<θ<25.03°. The refinement of structure for 14452 reflections was converged to final R=0.0378, wR=0.1025. The molecular structure consists of fourcoordinated tin atom in a slightly distorted tetrahedral configuration. The bioassay tests showed a high acaricidal activity of some compounds.

Key words: Tri(2-methyl-2-phenylpropyl)tinoxide derivatives, Synthesis, Crystal structure, Acarcidal activity

CLC Number:

O627.42

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ZHANG Zhao-Gui, HUANG Yan-Qin, ZOU Yang, ZHANG Shu-Kui, XIE Qing-Lan . Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives[J]. Chem. J. Chinese Universities, 2002, 23(3): 399.

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Studies on the Biological Activities and Synthesis of Tri(2-methyl-2-phenylpropyl)tinoxide Derivatives

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