Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (2): 182.

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Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion

LIU Hai-Yang¹, HU Xi-Ming¹, YING Xiao², WU Ting-Wan², WANG Wen-Jwu³, CHUANG Kuo-Shen³, LUO Chi-Fong³

1. Department of Applied Chemistry, South China University of Technology, Guangzhou 510641, China;
2. Departmemt of Physics, South China University of Technology, Guangzhou 510641, China;
3. Departmentof Chemistry, Tamkang University, Taipei 25137

Received:2001-02-26 Online:2002-02-24 Published:2002-02-24

Abstract

Abstract: Homogeneous solution of poor soluble aza-bridged bis-phenanthroline macrocyclic compound(H₂HAPP) was obtained by adding K₂CO₃ to its trifluoroacetate in CH₃OH-CH₂Cl₂[ V (CH₃OH): V (CH₂Cl₂)= 1:1] solution. Coordination reaction between H₂HAPPand metal ion Zn(Ⅱ) in CH₃OH CH₂Cl₂[ V (CH₃OH): V (CH₂Cl₂)=1:1] solvent was studied by UV-Vis spectroscopic method, which indicated 1:1 complexing between H₂HAPP and Zn(II) ion occurred easily in such a homogeneous system at room temperature. And the formation of ZnHAPPcomplex was further confirmed by FAB MS and ¹H NMR spectra.

Key words: Aza-bridged bis-phenanthroline macrocycle, Metal ion, Coordination reaction

CLC Number:

O614

TrendMD:

LIU Hai-Yang, HU Xi-Ming, YING Xiao, WU Ting-Wan, WANG Wen-Jwu, CHUANG Kuo-Shen, LUO Chi-Fong. Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion[J]. Chem. J. Chinese Universities, 2002, 23(2): 182.

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Studies of the Coordination Reaction Between Aza-bridged Bis-phenanthroline Macrocycle and Metal Ion

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