Synthesis of a Family of Ferrocene-bearing Cyclo-pseudo-peptides by Liquid Method and Molecular Recognition

Abstract

Abstract: Two series of new ferrocene-bearing cyclo-pseudo-peptides, including three 1+1 type and three 2+2 type compounds, were designed and synthesized by liquid method. The interactions of the 1+1 type cyclo-pseudo-peptides as the host compounds with some anions were investigated by cyclic voltammetry(CV) and ¹H NMR methods. The results show that the 1+1 type hosts can selectively interact with the guest anions by intermolecular hydrogen bond. A reasonable interaction model of the 1+1 type cyclo-pseudo-peptides with anions was proposed.

Key words: Cyclo-pseudo-peptides, Synthesis, Molecular recognition

CLC Number:

O625

TrendMD:

HAN Qian-Wei, ZHU Xiao-Qing, HU Xu-Bo, CHENG Jin-Pei . Synthesis of a Family of Ferrocene-bearing Cyclo-pseudo-peptides by Liquid Method and Molecular Recognition[J]. Chem. J. Chinese Universities, 2002, 23(11): 2076.

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Synthesis of a Family of Ferrocene-bearing Cyclo-pseudo-peptides by Liquid Method and Molecular Recognition

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