Fabrication of Ordered and Multilayer Film Electrode Containing Iron（Ⅲ） Porphyrin Based on Covalently Attached Interaction and Its Electrocatalytic Reduction to H2O2

Abstract

Abstract: Construction of a highly stable covalently attached multilayer film electrode containing iron(Ⅲ) porphyrin was achieved by UV irradiation of ionic self-assembled multilayer films of diazo-resins(DAR) and Fe(Ⅲ) tetrakis(p-sulfonatophenyl) porphyrin(FeTSPP). The fabricated processes of the multilayer film electrode were characterized by UV and IR spectra. The modified electrode has an excellent stability and a good catalytic activity toward electroreduction of H₂O₂.

Key words: Ordered molecular film, Covalently attached interaction, Iron(Ⅲ) porphyrin, Hydrogen peroxide, Electrocatalysis

CLC Number:

O657.1

TrendMD:

FU Ya-Qin, LI Xiao-Fang, SUN Chang-Qing . Fabrication of Ordered and Multilayer Film Electrode Containing Iron（Ⅲ） Porphyrin Based on Covalently Attached Interaction and Its Electrocatalytic Reduction to H₂O₂[J]. Chem. J. Chinese Universities, 2002, 23(11): 2055.

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Fabrication of Ordered and Multilayer Film Electrode Containing Iron（Ⅲ） Porphyrin Based on Covalently Attached Interaction and Its Electrocatalytic Reduction to H₂O₂

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