Chem. J. Chinese Universities ›› 2022, Vol. 43 ›› Issue (5): 20220063.doi: 10.7503/cjcu20220063

• Review • Previous Articles     Next Articles

Synthesis and Applications of Graphdiyne Based Zerovalent Atomic Catalysts

CHEN Zhaoyang1, XUE Yurui1(), LI Yuliang1,2()   

  1. 1.Science Center for Material Creation and Energy Conversion,School of Chemistry and Chemical Engineering,Institute of Frontier and Interdisciplinary Science,Shandong University,Jinan 250100,China
    2.Key Laboratory of Organic Solids,Institute of Chemistry Chinese Academy of Sciences,Beijing 100190,China
  • Received:2022-01-26 Online:2022-05-10 Published:2022-03-15
  • Contact: XUE Yurui,LI Yuliang E-mail:yrxue@sdu.edu.cn;ylli@iccas.ac.cn
  • Supported by:
    the National Key Research & Developmen Project of China(2018YFA0703501);the National Natural Science Foundation of China(21790050);the Key Project of Chinese Academy of Sciences(QYZDY-SSW-SLH015);the Qilu Young Scholars Fund of Shandong University, China, the Major Basic Research Project of Natural Science Foundation of Shandong Province, China(ZR2020ZD38);the Shandong Taishan Scholar Engineering Youth Expert Program, China(tsqn201909050);the Shandong Natural Science Foundation Outstanding Youth Program, China(ZR2021JQ07)

Abstract:

Atomic catalysts(ACs) are new types of catalysts with the characteristics of zerovalent metal atoms anchored on the substrates, and have been the research frontier in the field of catalysis due to their unique and fascinating properties such as higher atomic utilization, higher selectivity, excellent catalytic activity and stability. Graphdiyne(GDY) based zerovalent ACs are stabilized by the unique incomplete charge transfer between metal atoms and GDY, which solves the problem of easy migration and aggregation of traditional singe-atom catalysts. In this review, the synthesis, structures and characterizations of GDY based zerovalent atomic catalysts were first introduced. Next, the latest research advances of GDY based zerovalent atomic catalysts in many fields(e. g., the ammonia production, hydrogen production, overall water splitting, CO2 fixation and conversion, etc.) were discussed. This review provides an important research idea for the design and synthesis of new concept high-performance catalytic materials.

Key words: Graphdiyne, Atomic catalyst, Atomic catalysis, Electrocatalysis, Energy conversion

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