Synthesis and Characterization of Novel Functional Hyperbranched Polyesters

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (6): 1073.

• Articles • Previous Articles

Synthesis and Characterization of Novel Functional Hyperbranched Polyesters

TANG Li-Ming¹, HansR. Kricheldorf²

1. Dept. of Chem. Eng., School of Material Science and Engineering, Tsinghua University, Beijing 100084, China;
2. Institute of Technology and Macromolecule Chemistry, Hamburg University, Hamburg, Germany

Received:2000-06-09 Online:2001-06-24 Published:2001-06-24

Abstract

Abstract: Aseries of hyperbranched polyesters with controlled inherent viscosities have been prepared by polycondensation of 3,5-bis(trimethylsiloxy) benzoyl chloride with sililated p-methyl aniline under various molar ratios. After reacted with acid chlorides in o-dichlorobenzene, the functionalization of these polyesters was readily accomplished. The end groups of the crude polymers were effectively transferred into vinylic and ethynylic groups in high yields(>85%) as calculated by ¹H NMRspectra without any change in their inherent viscosities.

Key words: Hyperbranched polyester, Synthesis, Functionalization, End groups

CLC Number:

O631

TrendMD:

TANG Li-Ming, HansR. Kricheldorf . Synthesis and Characterization of Novel Functional Hyperbranched Polyesters[J]. Chem. J. Chinese Universities, 2001, 22(6): 1073.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[3]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[4]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[5]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[6]	GUO Zhiqiang, YANG Boru, XI Chanjuan. Recent Advances in Reductive Functionalization of Carbon Dioxide with Borohydride Reagents [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220199.
[7]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[8]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[9]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[10]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[11]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[12]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[13]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[14]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[15]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.

Synthesis and Characterization of Novel Functional Hyperbranched Polyesters

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments