Structure and Characterizations of the Inclusion Complex of Acylferrocene-2-furoylhydrazone with β-Cyclodextrin

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (5): 776.

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Structure and Characterizations of the Inclusion Complex of Acylferrocene-2-furoylhydrazone with β-Cyclodextrin

LIAO Zhi-Xin^1,2, ZHANG Yan-Ling¹, MA Xue-Yi¹, CHEN Yao-Zu^1,3, SHI Zhi-Xian²

1. National Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China;
2. Northwest Plateau Institute of Biology, Chinese Academy of Sciences, Xining 810001, China;
3. Institute of Organic Chemistry, Zhejiang University, Hangz hou 310072, China

Received:2000-03-22 Online:2001-05-24 Published:2001-05-24

Abstract

Abstract: Inclusion complex of acylferrocene-2-furoylhydrazone(AFH) with β-Cyclodextrin( β-CD) has been prepared by using kneading method. Elemental analysis and the solubility determination proved that₁:1 inclusion complex is formed. Characterizations of the inclusion complex were studied by UV, FTIRand X-ray diffractometry. The association constant to be 227.3 L·mol^-1 was calculated from the straight portion of the phase solubility diagram. The structure of the inclusion complex was investigated by NMRspectroscopy.

Key words: Acylferrocene-2-furoylhydrazone, β-Cyclodextrin, Inclusion complex

CLC Number:

O621

TrendMD:

LIAO Zhi-Xin, ZHANG Yan-Ling, MA Xue-Yi, CHEN Yao-Zu, SHI Zhi-Xian . Structure and Characterizations of the Inclusion Complex of Acylferrocene-2-furoylhydrazone with β-Cyclodextrin[J]. Chem. J. Chinese Universities, 2001, 22(5): 776.

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Structure and Characterizations of the Inclusion Complex of Acylferrocene-2-furoylhydrazone with β-Cyclodextrin

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