Synthesis of β-Cyclodextrin and Glucoside Compounds-bonded Porphyrins and Metal Porphyrins

Abstract

Abstract: The reaction of mono-6-hydroxy permethylated β-cyclodextrin(PM β-CD-CH₂OH) with trifluoromethanesulforic anhydride under N₂ gave mono 6 trifluoromethanesulfonate permethylated β-cyclodextrin(6). Compound 6 reacted with 5-( p aminophenyl)-10,15,20-triphenyl nickel porphyrin [NiTP_NH2 P](2) or 5-( p aminophenyl)₁₀,15,20 triphenyl carbonyl ruthenium porphyrin[Ru(CO)TP_NH2 P](3) to produce complexes 7 and 8. 1-Bromo-2,3,5-Oacetyl-β-D-furanoside(4) and 1-bromo-1,2,3,4,6-Oacetyl-α-D-pyranoglucoside(5) respectively reacted with H₂TP_NH2 P(1) to afford compounds 9 and 10. The new compounds 6—10 were identified by IR, UV-Vis, ¹H NMR, elemental analysis, in which compound 6 was determined by MSspectra.

Key words: β-Cyclodextrin, Glucoside compounds, Metal porphyrins, Synthesis

CLC Number:

O168.2

TrendMD:

LI Zao-Ying, LI Cong, LI Li, WANG Tie-Feng . Synthesis of β-Cyclodextrin and Glucoside Compounds-bonded Porphyrins and Metal Porphyrins[J]. Chem. J. Chinese Universities, 2000, 21(6): 840.

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Synthesis of β-Cyclodextrin and Glucoside Compounds-bonded Porphyrins and Metal Porphyrins

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