Synthesis and Spectrum Study of 4P-Hydroxymethyl- 2,6,7-trioxa-1,4-diphospha-bicyclo[2.2.2]-chlorooctane

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (2): 252.

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Synthesis and Spectrum Study of ⁴P-Hydroxymethyl- 2,6,7-trioxa-1,4-diphospha-bicyclo[2.2.2]-chlorooctane

HAN Jia-Xiang¹, LIU Jun¹, PU Min-Li², YUAN De-Kai¹, ZHANG Zhong-Wei¹, LI Yu-Gui¹

1. Instituteof Elemento-organic Chemistry, Nankai University, Tianjin 300071, China;
2. College of Materials Science&Engineering, Tianjin University, Tianjin 300072, China

Received:1999-03-11 Online:2000-02-24 Published:2000-02-24

Abstract

Abstract: Using THPCas the initial substrate, 2,6,7-trioxa-1,4-diphospha-bicyclo[2.2.2]-octane was gotten in strong basic environment by an indirect way. And then, after a series of reaction, the target Caged-diphospha-bicyclo compounds were synthesized using a new method. The whole procedure was reported in detail. Furthermore, the molecule structures and some spectra of the target compounds were also systematically described in this paper. Some valuable phenomena were discovered in ¹³P NMRspectra, such as the chemical shift from 2 to 5a and 5b, and the increase of ³J_{P_P}from 2 to 5.

Key words: Caged-diphospha-bicyclo compounds, Synthesis, Molecular structure, Spectrum charac-teristics

CLC Number:

O626.1

TrendMD:

HAN Jia-Xiang, LIU Jun, PU Min-Li, YUAN De-Kai, ZHANG Zhong-Wei, LI Yu-Gui. Synthesis and Spectrum Study of ⁴P-Hydroxymethyl- 2,6,7-trioxa-1,4-diphospha-bicyclo[2.2.2]-chlorooctane[J]. Chem. J. Chinese Universities, 2000, 21(2): 252.

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Synthesis and Spectrum Study of ⁴P-Hydroxymethyl- 2,6,7-trioxa-1,4-diphospha-bicyclo[2.2.2]-chlorooctane

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