Synthesis and Characteristics of Thienyltrifluroacetone-acylpyrazolone-phenanthroline-europium Chelate

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (10): 1527.

• Articles • Previous Articles Next Articles

Synthesis and Characteristics of Thienyltrifluroacetone-acylpyrazolone-phenanthroline-europium Chelate

ZHU Wei-Guo^1,2, YUAN Tong-Suo¹, WEI Xiao-Qiang¹, LU Zhi-Yun¹, HUANG Yan¹, LIU Yu^1,3, XIE Ming-Gui¹

1. Departmentof Chemistry, Sichuan University, Chengdu 610064, China;
2. Departmentof Chemistry, Xiangtan University, Xiangtan 411105, China;
3. Departmentof Chemistry, Qongzhou University, Qiongzhou 572200, China

Received:1999-08-10 Online:2000-10-24 Published:2000-10-24

Abstract

Abstract: Anovel chelate Eu(TTA)₂(PMTBBP)Phen, which contained ligand 1-pheny-3-methyl-4-(4'-t-butylbenzoyl)-5-pyrazolone(HPMTBBP), 4,4,4-trifluro-1-(2-thienyl)-1,3-butandione(HTTA) and phenanthroline(Phen), was synthesized. Its chemical structure was elucidated by IR, UV, ¹H NMR, MS, DSCand elementary analysis. The influence of acylpyrazolone on fluorescent intensity of the new chelate was studied. The results showed that Eu(TTA)₂(PMTBBP)Phen had more excellent PLproperties and better film formation than that of Eu(TTA)₃Phen.

Key words: Europium complex, Synthesis, Acylpyrazolone, Fluorescent property

CLC Number:

O614.33

TrendMD:

ZHU Wei-Guo, YUAN Tong-Suo, WEI Xiao-Qiang, LU Zhi-Yun, HUANG Yan, LIU Yu, XIE Ming-Gui. Synthesis and Characteristics of Thienyltrifluroacetone-acylpyrazolone-phenanthroline-europium Chelate[J]. Chem. J. Chinese Universities, 2000, 21(10): 1527.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[9]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[10]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[11]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[12]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[13]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[14]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.
[15]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.

Synthesis and Characteristics of Thienyltrifluroacetone-acylpyrazolone-phenanthroline-europium Chelate

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments