SnCl4Catalysed Oxidation of Acetone with Hydrogen Peroxide to Macrocyclo Peroxide

Abstract

Abstract: SnCl₄·5H₂Oand SnCl₂·2H₂O are the efficient catalysts for the oxidation of acetone with 30% hydrogen peroxide at room temperature to tetrametric acetone peroxide which is identified by molecular determination, elemental analysis, FT-IR, NMR, and MS. The catalytic activity of SnCl₄·5H₂O and SnCl₂·2H₂O is much higher than that of HCl. In the case of SnCl₄·5H₂O, the maximum yield of tetrametric acetone peroxide reaches 95.0%. The results show that the active species of catalytic reaction may be Sn⁴⁺.

Key words: Acetone, Hydrogen peroxide, SnCl₄·5H₂O, Catalytic oxidation, Macrocyclo peroxide

CLC Number:

O643.1

TrendMD:

JIANG Heng, LI Hai-Ying, HAN Xiao-Xiang, QIAO Qing-Dong . SnCl₄Catalysed Oxidation of Acetone with Hydrogen Peroxide to Macrocyclo Peroxide[J]. Chem. J. Chinese Universities, 1999, 20(3): 464.

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SnCl₄Catalysed Oxidation of Acetone with Hydrogen Peroxide to Macrocyclo Peroxide

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