Synthesis and Crystal Structure of In[(C2H5O)2PS2]3

Abstract

Abstract: The complex In[(C₂H₅O)₂PS₂]₃was synthesised and characterized by IR, MS, TGDTA and elementary analysis. The crystal structure was determined and indicated that In[(C₂H₅O)₂PS₂]₃is monoclinic, space group C2/c with a=0.8160(2) nm, b=1.8785(4) nm, c=1.7929(4)nm,α=γ=90.00(0)°, β=92.15(3)°, V=2.986(1) nm³, Z=4, D_x=1.538 g/cm³, F(000)=1360. The structure was refined to R=0.059 and R_w=0.063. There are four chemical units in each crystal celLIn which In(Ⅲ) ion coordinates with six sulfur atoms and the number of coordination is 6. The molecular contiguration of crystaLIs octahedral.

Key words: Indium, Di(2-ethyl)dithiophosphato, Monoclinic system, Space group C2/c

CLC Number:

O616

TrendMD:

LIU Xing-Zhi, XUE Hong, ZHAO Jin, SONG Yu-Lin, ZANG Shu-Liang . Synthesis and Crystal Structure of In[(C₂H₅O)₂PS₂]₃[J]. Chem. J. Chinese Universities, 1999, 20(2): 196.

[1]	HE Hongrui, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Density-functional Theoretical Study on the Interaction of Indium Oxyhydroxide Clusters with Carbon Dioxide and Methane [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220196.
[2]	LIU Hanlin, YIN Linlin, CHEN Xifeng, LI Guodong. Recent Advances in Indium Oxide Based Nanocatalysts for Selective Hydrogenation of CO₂ [J]. Chem. J. Chinese Universities, 2021, 42(5): 1430.
[3]	LIU Tianshuo, LONG Shichuan, YAO Zhiyi, SHI Jia, YANG Yang, HONG Wenjing. Progress of Charge Transport Through Self-assembled Monolayers by Employing Eutectic Gallium-Indium Technique [J]. Chem. J. Chinese Universities, 2020, 41(12): 2629.
[4]	ZHANG Yiqing, LIU Jiaxiang. Hydrothermal Preparation of Cubic ITO Powder and Its Photoelectric Performance^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1110.
[5]	DING Minjuan, HUANG Hui, YANG Ping. Preparation and Visible Light Photocatalytic Performance of Ordered Mesoporous Indium Dioxide/Reduced Graphene Oxide Nanocomposite^† [J]. Chem. J. Chinese Universities, 2015, 36(5): 989.
[6]	FU Min, LUAN Weiling, TU Shantung, MLECZKO Leslaw. Synthesis of Broad Color-emitting CuInS₂/ZnS Quantum Dots at Low Temperature [J]. Chem. J. Chinese Universities, 2015, 36(10): 1865.
[7]	SHEN Liyuan, WU Yanying, LIU Dajun, HE Xingquan. Synthesis and Third-order Nonlinear Optical Properties of Indiumphthalocyanine-functionalized Four-arm Star Polymethylmethacrylate^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 409.
[8]	TANG Jing, TIAN Xiao-Chun, LIU Yue-Qiang, LIN Jian-Hang. Nucleation Mechanism and Electrocatalysis of Pd NPs onto ITO Electrode in the Electrochemical Deposition Process [J]. Chem. J. Chinese Universities, 2012, 33(05): 1011.
[9]	YAN Xiao-Hui, DIAO Peng*, XIANG Min. Electrochemical Preparation of Shape-controlled Pd Nanoparticles and Their Electrocatalytic Properties [J]. Chem. J. Chinese Universities, 2011, 32(11): 2650.
[10]	TAN Ting-Feng, WANG Shi-Rong*, BAI Xiang, LI Xiang-Gao. Solid Synthesis and Photosensitive Properties of Chloroindium Phthalocyanine [J]. Chem. J. Chinese Universities, 2010, 31(6): 1167.
[11]	TIAN Zhen-Fen¹, SONG Tian-You^1,2, FAN Yong¹, HUANG Liang-Liang¹, WANG Li^1. Solvothermal Synthesis and Characterization of One-dimensional Chained Indium-Sulfate [J]. Chem. J. Chinese Universities, 2009, 30(3): 446.
[12]	LIU Cheng-Zhan^1,2, ZHU Guang-Shan¹, FANG Qiang-Rong¹, XUE Ming¹, SUN Fu-Xing¹, QIU Shi-Lun¹*. Hydrothermal Synthesis and Crystal Structure of [In₂(HPO₃)₄]·(NH₃CH₂CH₂NH₃) [J]. Chem. J. Chinese Universities, 2007, 28(9): 1637.
[13]	WU Zhi-Yong*, TIAN Xiao-Xi, QU Bai-Yan, CHEN Kun, FANG Fang. Self-heating and Sensing Static Chip Polymerase Chain Reaction(PCR) of Transparent Electro-conductive Glass Substrate(ITO) [J]. Chem. J. Chinese Universities, 2007, 28(12): 2259.
[14]	LIU Ying¹, CHEN Yu¹, FENG Miao^1,3, LIN Ying¹, Doyle J. J², Blau W. J.², CAI Liang-Zhen¹. Passive Optical Limiting Performance of Solid-State Polymer-Indium Phthalocyanine Composite Materials [J]. Chem. J. Chinese Universities, 2007, 28(11): 2092.
[15]	LIU Cheng-Zhan^1,2, ZHU Guang-Shan¹, JIN Zhao¹, XUE Ming¹, SUN Fu-Xing¹, FANG Qiang-Rong¹, QIU Shi-Lun¹*. Hydrothermal Synthesis and Characterization of a New Indium Phosphite [In₄(HPO₃)₇(H₂O)₃](NH₃CH₂CH₂NH₃)·(H₂O) with Intersectin [J]. Chem. J. Chinese Universities, 2007, 28(10): 1826.

Synthesis and Crystal Structure of In[(C₂H₅O)₂PS₂]₃

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments