Electronic Structure and Luminescent Property of Phenylenevinylene Dimers with Different Electron-releasing Substituents

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (10): 1633.

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Electronic Structure and Luminescent Property of Phenylenevinylene Dimers with Different Electron-releasing Substituents

SUN Jing-Zhi^1,2, CHEN Yu¹, WU Fang¹, MA Yu-Guang¹, TIAN Wen-Jing¹, SHEN Jia-Cong^1,2

1. Key Laboratory for Supramolecular Structure and Spectra, Jilin University, Changchun 130023, China;
2. Department of Chemistry, Jilin University, Changchun 130023, China

Received:1998-09-07 Online:1999-10-24 Published:1999-10-24

Abstract

Abstract: A series of phenylenevinylene dimers with different electron-releasing substituents were synthesized by Wittig reaction. Their electronic structures were characterized with cyclic-voltammetry and UV-V is spectra, their energy levels were calculated with a quantum chemical calculation approach (AM1), the relationship between the photoluminescent property and the electronic structure was systematically discussed.

Key words: Phenylenevinylene dimers, Electronic structure, Photoluminescent property

CLC Number:

O631

TrendMD:

SUN Jing-Zhi, CHEN Yu, WU Fang, MA Yu-Guang, TIAN Wen-Jing, SHEN Jia-Cong . Electronic Structure and Luminescent Property of Phenylenevinylene Dimers with Different Electron-releasing Substituents[J]. Chem. J. Chinese Universities, 1999, 20(10): 1633.

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Electronic Structure and Luminescent Property of Phenylenevinylene Dimers with Different Electron-releasing Substituents

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