Molecular Recognition Study on Supramolecular System(ⅩⅦ) Inclusion Complexation of Some β-Cyclodextrin Derivatives Containing Organo selenium with Aliphatic Alcohols

Abstract

Abstract: The spectrophotometric titrations have been performed at 298.15 Kin buffered aqueous solution(pH=7.20) to give the stability constants(lg K_s) for the supramolecular system formed by mono-[6-phenylseleno)-6-deoxy]-β-cyclodextrin(1), nono-[6-( p-chlorophenylseleno)-6-deoxy]-β-cyclodextrin(2), mono-[6-(naphthylseleno)-6-deoxy] β-cyclodextrin(3), and mono-[6-(benzylseleno)-6-deoxy] β-cyclodextrin(4) with a series of aliphatic alcohols.

Key words: Cyclodextrin, Organo selenium modified cyclodextrin, Molecular recognition, Aliphatic alcohols

CLC Number:

O641.4

TrendMD:

LIU Yu, LI Bin, LI Zi-Yun, LI Jing . Molecular Recognition Study on Supramolecular System(ⅩⅦ) Inclusion Complexation of Some β-Cyclodextrin Derivatives Containing Organo selenium with Aliphatic Alcohols[J]. Chem. J. Chinese Universities, 1998, 19(9): 1440.

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Molecular Recognition Study on Supramolecular System(ⅩⅦ) Inclusion Complexation of Some β-Cyclodextrin Derivatives Containing Organo selenium with Aliphatic Alcohols

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