Synthesis and Crystal Structure of 1,1,4,4-Tetrachloro-1a,3-diphenyl-1a,2,3,4-tetrahydro-1H-Azirino[2,1-e][1,6]benzothiazocine

Abstract

Abstract: Title compound was synthesized by insertion and cycloaddition reaction of 2,4-diphenyl-2,3-dihydro-1,5-benzothiazepine and dichlorocarbene generated from chloroform under the alkaline condition and its crystal structure was determined by X-ray diffraction method. The single crystals belong to orthogonal, space group Pc2₁ /n with a = 1.0243(2) nm, b = 1.1451(2) nm, c = 1.8388(3) nm, V = 2. 1570(5) nm³, Z =4, D_c=1.693 g·cm^-3, μ =0.066 mm^-1, F (000)= 1066 for 2467 reflections, R =0.039, R_w=0.054.

Key words: 1a,2,3,4 Tetrahydro-1H-azirino[2,1-e][1,6]benzothiazocine, Crystal structure, Molecular structure

CLC Number:

O641

TrendMD:

XU Jia-Xi, LAN Ruo-Xi, JIN Sheng . Synthesis and Crystal Structure of 1,1,4,4-Tetrachloro-1a,3-diphenyl-1a,2,3,4-tetrahydro-1H-Azirino[2,1-e][1,6]benzothiazocine[J]. Chem. J. Chinese Universities, 1998, 19(11): 1774.

References

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