Synthesis and Crystal Structure of Organometallic Salt [CpFe(C6H6)]2·[Ni(mnt)2]

Abstract

Abstract: Organometallic salt[CpFe (C₆H₆)]₂·[Ni (mnt)₂] was synthesized by the metathetical reaction of [CpFe (C₆H₆) ]PF₆ with Na₂[Ni (mnt)₂]. It was characterized by elementary analysis, IR and ¹H NMR spectra. The structure of this compound was determined by X-ray single crystal diffraction analysis. The crystallographic data are as follows: triclinic,space group P1, α=0. 838(2) nm, b=1. 084(6)nm, c=1. 816(7) nm,α=83. 41 (4)°, β=89. 30(3)°,γ= 80. 22(3)°, Z= 2. The cations exist in two directions, which are perpendicular to each other. The anions also exist in two directions, which form a dihedral angle of 75. 4°. Conductivity measurements of the compound showed a semiconductor behavior with a conductivity of 4.1×10^-5 S·cm^-1 at room temperature.

Key words: Organometallic salt, Synthesis, Crystal structure

CLC Number:

O614.81

TrendMD:

YANG Chu-Luo, MA Sheng-Gang, QIN Jin-Gui, LIU Dao-Yu, LUO Bao-Sheng . Synthesis and Crystal Structure of Organometallic Salt [CpFe(C₆H₆)]₂·[Ni(mnt)₂][J]. Chem. J. Chinese Universities, 1998, 19(1): 61.

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Synthesis and Crystal Structure of Organometallic Salt [CpFe(C₆H₆)]₂·[Ni(mnt)₂]

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