Studies on the Formation of Charge Transfer Complex Between Fullerene and Zinc Phthalocyanine

Abstract

Abstract: The system of ZnPc-C₆₀ ln speclal mixed organic solvents has been studled by UVVis, fluorescence and laser Raman spectra. The results prove the existence of a chargetransfer complex (CTC) by the lnteractlon between ZnPc and C₆₀ The molar ratio of ZnPc/C₆₀ in CTCis 2: 1. The formation equilibrium constant(K) was determined at 25 C. Mea-surements of photovoltaic effect show that ZnPc-C₆₀ CTCleads to a rernarkable enhancementof photosensitivity comparing to that of ZnPc.

Key words: Fullerene, Zinc phthalocyanine, Charge transfer complex, Photovoltaic effect

CLC Number:

O646

TrendMD:

CHEN Zai-Hong, XIE Yong-Ming, LI Juan, ZHAN Meng-Xiong. Studies on the Formation of Charge Transfer Complex Between Fullerene and Zinc Phthalocyanine[J]. Chem. J. Chinese Universities, 1997, 18(9): 1534.

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Studies on the Formation of Charge Transfer Complex Between Fullerene and Zinc Phthalocyanine

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