The Heterometallic Cluster Catalyzing Coordinative Hydrogenation and Isomerization Promoted by Oxygen Transfer Reagent

Abstract

Abstract: The oxygen transfer reagent (OTR), Me₃NO.2H₂Oand PhIO, can promote thecoordinative hydrogenation and isomerization of 1-hexane catalyzed by heterometallic car-bonyl clusters, SRuCO₂ (CO)₉ and SeRuCo₂ (CO)₉.The tetrahedral skeleton of the catalystkeeps intact in catalysis process.In methanol solution, [1-Hexene]/[Cat.] = 200,[Me₃NO.2H₂O]/[Cat.] = 4, PH₂ = 5.06.0 MPa, 60℃ and in 24 h are the best condi-tions.Aplausible mechanism is given.

Key words: Heteromettallic carbonyl cluster, 1-Hexene, Hydrogenation, Oxygen transfer reagent, Homogeneous catalysis

CLC Number:

O643.32

TrendMD:

LI Qing-Shan, DING Er-Run, LIU Sheng-Ming, YIN Yuan-Qi. The Heterometallic Cluster Catalyzing Coordinative Hydrogenation and Isomerization Promoted by Oxygen Transfer Reagent[J]. Chem. J. Chinese Universities, 1997, 18(7): 1007.

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The Heterometallic Cluster Catalyzing Coordinative Hydrogenation and Isomerization Promoted by Oxygen Transfer Reagent

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