Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (6): 981.

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Rheological Properties and In-situ Reinforcement of Liquid Crystalline Copolyesteramide/Poly(ethylene terephthalate) Blends

XIE Xiao-Lin1, WU Da-Cheng2   

  1. 1. State Key Lab of Polym. Reaction Eng., Institute of Polym. Sci. and Eng., Zhejiang University, Hangzhou, 310027;
    2. Light Textile College, Sichuan Union University, Chengdu, 610065
  • Received:1995-06-17 Online:1997-06-24 Published:1997-06-24

Abstract: The binary blends of liquid crystalline copolyesteramide(PEA) and poly(ethyleneterephthalate, PET) were studied by Instron3211 type capillary rheometer, The spinnability of the blend melts was inverstigated based on their rheological properties- The relationship between the mechanical properties and structure was discussed. The results show that the viscosity of blends is lower than that of PETand there is a minimum of viscosity at 10%PEAcontent. When the content of PEAis less than 10%, the blends are well-spinnable,and the composite fibers have a well-developed highly oriented fibrillar structure along the fiber axis. As the PEAis 5%, good in-situ reinforcement can be obtained.

Key words: Liquid crystalline copolyesteramide, Poly(ethylene terephthalate), Blends, Rheology, In-sltu reinforcement

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