Amberlite XAD-2 Resin Microcolumn Coupled On-line to a Flow Injection Approach for the Preconcentration, Clean-up and Determination of Trace Phenols in Waters

Abstract

Abstract: Anovel and expeditious approach for direct determination of phenols in water andwaste water based on solid-phase extraction coupled to a flow injection analysis (FIA)manifold is described. The method employs on-line preconcentration of phenols using a 3 cm×3mm column packed with Amberlite XAD-2 resin. The phenols are subsequently eluted fromthe resin into a flowing system with an alkaline solution and quantifiedspectrophotometrically as the products of reaction with 4-aminoantipyrine (4-AAP) system. Thesensitivity offered by the procedure was higher by a factor of pH=13 than that provided by aconventional FIAmethod.

Key words: Phenols, Waste water, Solid-phase extraction, Flow system

CLC Number:

O652.6

TrendMD:

SONG Wen-Lu, WANG Lian-Sheng, ZHI Zheng-Liang. Amberlite XAD-2 Resin Microcolumn Coupled On-line to a Flow Injection Approach for the Preconcentration, Clean-up and Determination of Trace Phenols in Waters[J]. Chem. J. Chinese Universities, 1997, 18(10): 1621.

[1]	JIN Keyan, BAI Pu, LI Xiaolong, ZHANG Jianan, YAN Wenfu. New Mg-Al Type Sorbent for Efficient Removal of Boron from Waste Water Containing High-concentration of Boron from Pressurized Water Reactor Nuclear Power Plants [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210516.
[2]	YUAN Li, LI Zengzeng, JIANG Shengming, ZHU Yong, XIA Lülu, LI Lan, ZHAO Chuanqi, JIANG Ting, LEI Qian, TANG Shi. Visible-light-induced ortho-Perfluoroalkylation of para-Substituted Phenols and Anilines^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 241.
[3]	WEI Lanlan, YAN Yan, KANG Xuejue. Application of Packed-nanofibers Solid-phase Extraction for Determination of Rhodamine B in Dry Chilli, Fruit Drink and Red Wine [J]. Chem. J. Chinese Universities, 2017, 38(6): 935.
[4]	WANG Wenliang, GENG Jing, LI Lufei, CHANG Jianmin. Catalytic Properties of Fast Pyrolysis Char Loaded with Cu-Zn on Alkali Lignin Pyrolysis for Monophenols^† [J]. Chem. J. Chinese Universities, 2016, 37(4): 736.
[5]	WANG Xinxin, LÜ Xia, GE Guangbo, FENG Lei, XIN Hong, LI Yaoguang, CAO Yunfeng, HAN Guanying, GUO Bin. Highly Efficient Preparation of Resorufin-β-D-glucuronide^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1321.
[6]	CHEN Haiyan, DING Lan, LIU Milan. Preparation of Molecularly Imprinted Polymers by Microwave-assisted Polymerization for the Extraction of Chloramphenicol from Honey^† [J]. Chem. J. Chinese Universities, 2015, 36(1): 67.
[7]	YANG Gang, ZHU Liangliang, LÜ Xia, WU Dachang, XIA Yangliu, MA Xiaochi, XIN Yi, HOU Jie. Highly Efficient Preparation of Bisphenol A Glucuronide^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 314.
[8]	DING Yao-Ying, WANG Cheng-Zhi, WEN Xian-Fang, ZHANG Xin-Peng, YE Lin, ZHANG Ai-Ying, FENG Zeng-Guo. Preparation of Amidoxime Modified Polyacrylonitrile Nanofibers and Its Application in Metal-ion Containing Waste Water Treatment [J]. Chem. J. Chinese Universities, 2013, 34(7): 1758.
[9]	LIU Jian-Lin, ZHANG Chen, WANG Xia-Jiao, WANG Ting, LI Yu. Carbon Nanotubes Assisted Solid-phase Extraction Combined with Dispersive Liquid-liquid Microextraction Based on Solidification of Floating Organic Droplet Method for the Determination of Trace Level Environmental Estrogens in Aqueous Solutions [J]. Chem. J. Chinese Universities, 2012, 33(01): 37.
[10]	ZENG Zhi, GUAN Shao-Wei, ZHU Shi-Yang, DAI Zhong-Ming, JIANG Zhen-Hua*. Synthesis of New Aromatic Trithiol for the Thiol–ene Ultraviolet-Curable Formulations [J]. Chem. J. Chinese Universities, 2011, 32(2): 407.
[11]	ZHANG Zhao-Hui, ZHANG Ming-Lei, XU Tian-Zhen, LUO Li-Juan, YANG Xiao, .... Microwave-assisted Heating Preparation of Core-shell Ion-imprinted Polymer and Extraction of Cr(Ⅲ) from Urine [J]. Chem. J. Chinese Universities, 2010, 31(9): 1734.
[12]	YIN Xue-Yan1, XU Qian1,2*, WU Shu-Yan1, WANG Min1, GU Zhong-Ze2. Determination of Phthalate Esters in Commercial Milk Samples Using PA6 Nanofibers Mat-based Solid-phase Extraction Coupled with Liquid Chromatography [J]. Chem. J. Chinese Universities, 2010, 31(4): 690.
[13]	PENG Chang, LIU Wei-Juan, ZHANG Chun-Tao, ZHANG Ling, ZHANG Zhi-Chao. Preparation of a Fragment Imprinted Polymer for Recognition of Triazole Pesticides and Its Application to Solid-phase Extraction [J]. Chem. J. Chinese Universities, 2009, 30(11): 2159.
[14]	XU Yi^1,2,3*, ZHANG Jian^1,2, ZHANG Wen-Pin^1,2,3, ZHANG Zhong-Feng¹, WEN Zhi-Yu^2,3 . Construction of Pretreatment Units with Esterified Silica Monolithic Column and Affinity Membrane on Micro-fluidic Chip [J]. Chem. J. Chinese Universities, 2008, 29(5): 892.
[15]	LI Li, HU Shu-Guo, HE Xi-Wen, LI Wen-You, CHEN Lang-Xing, ZHANG Yu-Kui. Solid-phase Extraction of Active Component of Chinese Traditional Medicine Fisetin by Using Molecularly Imprinted Polymers [J]. Chem. J. Chinese Universities, 2006, 27(4): 608.

Amberlite XAD-2 Resin Microcolumn Coupled On-line to a Flow Injection Approach for the Preconcentration, Clean-up and Determination of Trace Phenols in Waters

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments