Polymerization of MMA Initiated by PVC with Pendent N,N-Diethyldithiocarbamate Groups Under UV-Irradiation

Abstract

Abstract: The PVCcontaining N,N-diethyldithiocarbamate groups(PVC-SR)was prepared by the substitution of sodium N, N-diethyldithiocarbamate on the partial chloride of PVCand used to initiate the polymerization of MMAunder UV-irradiation.The effects of irradiation time, concentration of monomer, amount and degree of functionality of PVC-SR on the polymerization were investigated.The results showed that PVC-SRcould efficiently initiate the photopolymerization of MMA to form crosslinked graft copolymers which had a high grafting efficiency and a high degree of gel .

Key words: N,N-Diethyldithiocarbamate, Polyvinyl chloride, Grafting polymerization, Photopolymerization

TrendMD:

YANG Wen-Jun, GUAN Jian-Jun, YE Shu, CUI Wei-Guo, SHEN Jia-Cong. Polymerization of MMA Initiated by PVC with Pendent N,N-Diethyldithiocarbamate Groups Under UV-Irradiation[J]. Chem. J. Chinese Universities, 1996, 17(9): 1473.

[1]	ZUO Xiaoling, WU Chong, HUANG Anrong, LUO Jiaolian, LI Zhuyu, WANG Meng, ZHOU Ying, YU Hongna, GUO Jianbing. Visible-light-sensitive Versatile Fluorescent Brightener-based Photoinitiating Systems ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 811.
[2]	LIU Zhi, LI Bingrui, PAN Yanxiong, SHI Kai, WANG Weicai, PENG Chao, WANG Zhe, JI Xiangling. Adsorption Behavior of Hydrophilic Luffa Sponges to Heavy Metal Ions in Water System^† [J]. Chem. J. Chinese Universities, 2017, 38(4): 669.
[3]	LI Wei, WU Suhua, Ren Xinxin. Effect of Co-stabilizers on the Properties of Ba/Zn System [J]. Chem. J. Chinese Universities, 2017, 38(11): 2089.
[4]	WANG Dandan, LIU Junbo, CHANG Haibo, TANG Shanshan. Visible Photocatalytic Degradation of Polyvinyl Chloride Film by AgNbO₃ Photocatalyst^† [J]. Chem. J. Chinese Universities, 2014, 35(9): 1975.
[5]	GONG Mei, ZHANG Li, HUANG Di, DU Jingjing, ZHOU Minbing, LI Yubao, XIE Huiqi. Grafting Modification and Thermosensitive Properties of Polyurethane Microspheres^† [J]. Chem. J. Chinese Universities, 2014, 35(8): 1843.
[6]	SHI Suqing, YANG Yang, CAI Tianyuan, GAO Na, GONG Yongkuan, NIE Jun. Flavone/Tertiary Amine as Free Radical Photoinitiator for UV Photopolymerization of Tripropylene Glycol Diacrylate(TPGDA)^† [J]. Chem. J. Chinese Universities, 2014, 35(3): 660.
[7]	HUO Dan-Qun, FANG Ke-Jing, HOU Chang-Jun, YANG Mei, FA Huan-Bao, HUANG Cheng-Hong, LUO Xiao-Gang. Rapid Fabrication of Hydrogel Microfluidic Chip and Its Application for Cell Metabolites Detection [J]. Chem. J. Chinese Universities, 2013, 34(6): 1327.
[8]	ZHANG Jia-An, YANG Nian-Fa, YANG Li-Wen, GONG Hang, LIU Yan-Ling. Synthesis of Chiral (-)-Bis(menthylformyl)phenylphosphine Oxide and Its Helix-sense-selective Initiating Function for Radical Photopolymerization [J]. Chem. J. Chinese Universities, 2012, 33(08): 1727.
[9]	PENG Hai-Yan, BI Shu-Guang, LIAO Yong-Gui, ZHOU Xing-Ping, XIE Xiao-Lin. Photopolymerization Kinetics of Acrylate/Liquid Crystal Mixtures Initiated by Ketocoumarin/Amine/Triazine Ternary Photoinitiator [J]. Chem. J. Chinese Universities, 2012, 33(03): 640.
[10]	ZHANG Yong, SHI Wen-Fang. Synthesis and Photopolymerization Properties of Self-initiated Photopolymerized Acrylate Oligomers [J]. Chem. J. Chinese Universities, 2012, 33(03): 635.
[11]	SHI Xiao-Jing, PENG Hai-Yan, LIAO Yong-Gui, XIE Xiao-Lin*. Kinetics of Photopolymerization for the Acrylate/Liquid Crystal Mixture [J]. Chem. J. Chinese Universities, 2011, 32(6): 1407.
[12]	ZHAO Ning, SUN Yu-Ming, ZHANG Yuan-Hong, ZHANG Bao-Qin, YU Xiao-Qiang*, .... Capturing Radical Signal of Two-photon Initiated Photopolymerization of Vinyl Monomer by Means of ESR Technique [J]. Chem. J. Chinese Universities, 2010, 31(7): 1285.
[13]	CHEN Na¹, ZHANG Yu-Ping^2*, ZHANG Yi-Jun², YE Xiong-Wen¹, QU Ling-Bo¹, YUAN Zhuo-Bin^3,1. Rapid Preparation of Methacrylate Capillary Monolithic Columns by Photopolymerization [J]. Chem. J. Chinese Universities, 2008, 29(10): 1969.
[14]	LIU Xiao-Xuan^1,2*, JING Yan-Ni², BAI Ying-Kun², WU Guang-Guo². Controlled/Living Photopolymerization of Methyl Methacrylate in Miniemulsion Mediated by HTEMPO [J]. Chem. J. Chinese Universities, 2007, 28(4): 774.
[15]	ZHANG Zhi-Sen;ZHANG Xiao-Hua;XU Wei-Jian*;XIONG Yuan-Qin; ZHANG Zheng-Hua; XIA Xin-Nian. Synthesis and Characterization of a Novel Trifunctional Cycloaliphatic Epoxide Resin and Its Photosensivity of Cationic Photopolymerization [J]. Chem. J. Chinese Universities, 2006, 27(7): 1380.

Polymerization of MMA Initiated by PVC with Pendent N,N-Diethyldithiocarbamate Groups Under UV-Irradiation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments