Preparation of Nanoparticulate [PMo11Cu(H2O)O39]5--n-C18H37NH2 Film Using Langmuir-BIodgett Method

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (S1): 13.

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Preparation of Nanoparticulate [PMo₁₁Cu(H₂O)O₃₉]^5--n-C₁₈H₃₇NH₂ Film Using Langmuir-BIodgett Method

PENG Xiao-gang¹, ZHANG Xin-tong¹, LI Lin-song¹, QIN Zhu-jie¹, XIAO Liang-zhi¹, LI Tie-jin¹, Shen Chao²

1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
2. Department of of Fundamental Science, Jiamusi Institute of Technology Jiamusi, 154007, P, R. China

Received:1995-08-03 Online:1995-12-31 Published:1995-12-31
Supported by:
National Natural Science Foundation of China

Abstract

Abstract:

Nanoparticulate [PMo₁₁Cu(H₂O)O₃₉]^5--(PCuMo₁₁)-n-C₁₈H₃₇NH₂ composite monolayer can be formed at the air-liquid interface using nanoparticulate PCuMo₁₁ as the subphase. The area extrapolated to π=0 is 0.27 nm² per hydrocarbon chain of the monolayer. The collapse pressure is about 3.5×10^-1 N. The composite monolayer was deposited on the solid substrate using the LB technique. The XPS characterization of the composite monolayer showed that in the film the directional alignment of PCuMo₁₁, molecules was in the direction of Cu atoms close to the amino groups of the octadecylamine moleculos.

Key words: PCuMo₁₁-n-C₁₈H₃₇NH₂ composite monolayer, XPS, LB technique, Nanoparticle

TrendMD:

PENG Xiao-gang, ZHANG Xin-tong, LI Lin-song, QIN Zhu-jie, XIAO Liang-zhi, LI Tie-jin, Shen Chao. Preparation of Nanoparticulate [PMo₁₁Cu(H₂O)O₃₉]^5--n-C₁₈H₃₇NH₂ Film Using Langmuir-BIodgett Method[J]. Chem. J. Chinese Universities, 1995, 16(S1): 13.

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Preparation of Nanoparticulate [PMo₁₁Cu(H₂O)O₃₉]^5--n-C₁₈H₃₇NH₂ Film Using Langmuir-BIodgett Method

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