SERS Studies on the Orientation and Structure of Absorbed Water at Ag Electrodes──Effects of Electrode Potential and NaClO4Concentrations

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (2): 245.

• Articles • Previous Articles Next Articles

SERS Studies on the Orientation and Structure of Absorbed Water at Ag Electrodes──Effects of Electrode Potential and NaClO₄Concentrations

ZOU Shou-Zhong, ZHANG Yun-Hong, CHEN Yan-Xia, TIAN Zhong-Qun

State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen, 361005

Received:1994-06-04 Revised:1994-11-16 Online:1995-02-24 Published:1995-02-24

Abstract

Abstract: Combining with the special procedure of roughing surface and the difference spectra technique,one can obtain the surface enhanced Raman scattering(SERS) spectra of water adsorbed on Ag electrodes in a wide potential range(-0.7--2.0V) from NaClO₄solutions with various concentrations(0.1-8.0 mol/L).It has been shown that the absorbed water has much higher ordered structure than that in the bulk solutions.The concentration of NaClO₄has much less effect on water molecules adsorbed on the surface,especially in the relatively negative potential region,in comparison with that in the bulk solutions.With changing the potential form-2.0 Vto-0.9 V,the adsorbed water is reoriented from one hydrogen ending to the surface to two hydrogens then to the oxygen ending.The concentration effect of ClO₄^-ions on the reorientation of the absorbed water is discussed in detail.

Key words: Surface Enhanced Raman Scattering(SERS), H₂O,NaClO₄, Adsorption, Orientation

TrendMD:

ZOU Shou-Zhong, ZHANG Yun-Hong, CHEN Yan-Xia, TIAN Zhong-Qun. SERS Studies on the Orientation and Structure of Absorbed Water at Ag Electrodes──Effects of Electrode Potential and NaClO₄Concentrations[J]. Chem. J. Chinese Universities, 1995, 16(2): 245.

[1]	JIANG Hongbin, DAI Wenchen, ZHANG Rao, XU Xiaochen, CHEN Jie, YANG Guang, YANG Fenglin. Research on Co₃O₄/UiO-66@α-Al₂O₃ Ceramic Membrane Separation and Catalytic Spraying Industry VOCs Waste Gas [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220025.
[2]	HAO Honglei, MENG Fanyu, LI Ruoyu, LI Yingqiu, JIA Mingjun, ZHANG Wenxiang, YUAN Xiaoling. Biomass Derived Nitrogen Doped Porous Carbon Materials as Adsorbents for Removal of Methylene Blue in Water [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220055.
[3]	WANG Hongning, HUANG Li, QING Jiang, MA Tengzhou, JIANG Wei, HUANG Weiqiu, CHEN Ruoyu. Activation of Biochar from Cattail and the VOCs Adsorption Application [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210824.
[4]	MENG Xianglong, YANG Ge, GUO Hailing, LIU Chenguang, CHAI Yongming, WANG Chunzheng, GUO Yongmei. Synthesis of Nano-zeolite and Its Adsorption Performance for Hydrogen Sulfide [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210687.
[5]	XIA Dacheng, ZHOU Rui, TU Bo, CAI Zhiwei, GAO Nan, JI Xiaoxu, CHANG Gang, REN Xiaoming, HE Yunbin. Fabrication of Ag/Au Nanowires Array as a SERS Substrate for High-sensitivity Malachite Green Detection [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210731.
[6]	CHEN Xiaolu, YUAN Zhenyan, ZHONG Yingchun, REN Hao. Preparation of Triphenylamine Based PAF-106s via Mechanical Ball Milling and C2 Hydrocarbons Adsorption Property [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210771.
[7]	TAN Lejian, ZHONG Xuanshu, WANG Jin, LIU Zongjian, ZHANG Aiying, YE Lin, FENG Zengguo. Low Critical Dissolution Temperature Behavior of β⁃Cyclodextrin and Its Application in the Preparation of β⁃Cyclodextrin Sheet Crystal with Ordered Nano⁃channel [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220405.
[8]	ZHENG Meiqi, MAO Fangqi, KONG Xianggui, DUAN Xue. Layered Double Hydroxides as Sorbent for Remediation of Radioactive Wastewater [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220456.
[9]	TIAN Xiaokang, ZHANG Qingsong, YANG Shulin, BAI Jie, CHEN Bingjie, PAN Jie, CHEN Li, WEI Yen. Porous Materials Inspired by Microbial Fermentation： Preparation Method and Application [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220216.
[10]	MA Jianxin, LIU Xiaodong, XU Na, LIU Guocheng, WANG Xiuli. A Multi-functional Zn（II） Coordination Polymer with Luminescence Sensing， Amperometric Sensing， and Dye Adsorption Performance [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210585.
[11]	ZHANG Chi, SUN Fuxing, ZHU Guangshan. Synthesis， N₂ Adsorption and Mixed-matrix Membrane Performance of Bimetal Isostructural CAU-21 [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210578.
[12]	LI Weiqing, JIN Lei, YANG Jiaqiang, Wang Zhaoyun, YANG Fangzu, ZHAN Dongping, TIAN Zhongqun. Effects of Additive on the Electrodeposition and Coating Structure in a Novel System of Electronic Copper Electroplating [J]. Chem. J. Chinese Universities, 2021, 42(9): 2919.
[13]	LI Yichuan, ZHU Guofu, WANG Yu, CHAI Yongming, LIU Chenguang, HE Shengbao. Effects of Substrate Surface Properties and Precursor Chemical Environment on In⁃situ Oriented Construction of Titanium Silicalite Zeolite Membranes [J]. Chem. J. Chinese Universities, 2021, 42(9): 2934.
[14]	LIU Changhui, LIANG Guojun, LI Yanlu, CHENG Xiufeng, ZHAO Xian. Density Functional Theory Study of NH₃ Adsorption on Boron Nanotubes [J]. Chem. J. Chinese Universities, 2021, 42(7): 2263.
[15]	WANG Hongning, HUANG Li, SONG Fujiao, ZHU Ting, HUANG Weiqiu, ZHONG Jing, CHEN Ruoyu. Synthesis and VOCs Adsorption Properties of Hollow Carbon Nanospheres [J]. Chem. J. Chinese Universities, 2021, 42(6): 1704.

SERS Studies on the Orientation and Structure of Absorbed Water at Ag Electrodes──Effects of Electrode Potential and NaClO₄Concentrations

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments