Studies on Tailed Metalloporphyrin Coordination Compounds(Ⅲ)──The Synthesis and Properties of an Imidazolyl Tailed Porphyrin and Its Iron(Ⅲ) Coordination Compound

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (2): 163.

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Studies on Tailed Metalloporphyrin Coordination Compounds(Ⅲ)──The Synthesis and Properties of an Imidazolyl Tailed Porphyrin and Its Iron(Ⅲ) Coordination Compound

HUANG Jin-wang, LIU Jun-Feng, JIAO Xiang-Dong, JI Liang-Nian

Department of Chemistry, Biotechnology Research Center, Zhongshan University, Guangzhou, 510275

Received:1994-03-01 Revised:1994-08-19 Online:1995-02-24 Published:1995-02-24

Abstract

Abstract: Aimidazolyl tailed porphyrin,5-[o-(1-imidazolyl) butoxy]phenyl-10,15,20-triphenyl porphyrin(o-ImBPTPP),and its iron(Ⅲ) coordination compound(Fe(Ⅲ)(o-ImBPTPP)Cl) were synthesized and identified by elementary analysis and mass spectrometry.The structures were confirmed by IR、¹HNMR and UV-vis spectrometries.The coordinations of Fe(Ⅲ)(o-ImBPTPP) Cl with some nitrogeous ligands were studied.Usually Fe(Ⅲ)(o-ImBPTPP)Cl formed low-spin six-coordinate adducts with nitrogeous,but it could form a stable high-spin five-coordinate adduct with imidazole in benzene when the concentration of imidazole was lower.

Key words: Tailed porphyrin, Tailed iron(Ⅲ) porphyrin, Synthesis, Properties

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HUANG Jin-wang, LIU Jun-Feng, JIAO Xiang-Dong, JI Liang-Nian. Studies on Tailed Metalloporphyrin Coordination Compounds(Ⅲ)──The Synthesis and Properties of an Imidazolyl Tailed Porphyrin and Its Iron(Ⅲ) Coordination Compound[J]. Chem. J. Chinese Universities, 1995, 16(2): 163.

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Studies on Tailed Metalloporphyrin Coordination Compounds(Ⅲ)──The Synthesis and Properties of an Imidazolyl Tailed Porphyrin and Its Iron(Ⅲ) Coordination Compound

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