Crystal and Molecular Structure of m-Aminophenyl Boronic Acid Hydrochloride

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (12): 1841.

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Crystal and Molecular Structure of m-Aminophenyl Boronic Acid Hydrochloride

LI Hong-Feng¹, WANG Xiang-Yun¹, YANG Qing-Chuan², LIU Yuan-Fang¹

1. Technical Physics Department of Peking University, Beijing, 100871;
2. Chemistry Department of Peking University, Beijing, 100871

Received:1994-12-07 Revised:1995-05-28 Online:1995-12-24 Published:1995-12-24

Abstract

Abstract: The crystal and molecular structure of m-aminophenyl boronic acid (m-APBA)hydrochloride was determined by single crystal X-ray diffraction.The crystal parameters are as follows:monoclinic,space group P2₁/c,a=5.193 (3)nm,b=15.802(14) nm, c=10. 307(8)nm, Z=4.Each chloride ion is connected with 4 m-APBAH⁺ions through three Cl…H…Nhydrogen bonds and a Cl…H…Ohydrogen bond.Its coordination number is 4.The arrangement of m-APBA·HCl molecules within the crystal cell is determined by hydrogen bonding.

Key words: m-Aminophenyl boronic acid, Crystal structure, Molecular structure

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LI Hong-Feng, WANG Xiang-Yun, YANG Qing-Chuan, LIU Yuan-Fang. Crystal and Molecular Structure of m-Aminophenyl Boronic Acid Hydrochloride[J]. Chem. J. Chinese Universities, 1995, 16(12): 1841.

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Crystal and Molecular Structure of m-Aminophenyl Boronic Acid Hydrochloride

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