Studies on the Readions of Iron Carbonyl-Mercaptan(Thiophenol)-Grignard Reagent System with Benzoyl Chlorides─Syntheses and Structures of Some Substituted μ- Benzoyl Fe/S Complexes

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (9): 1331.

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Studies on the Readions of Iron Carbonyl-Mercaptan(Thiophenol)-Grignard Reagent System with Benzoyl Chlorides─Syntheses and Structures of Some Substituted μ- Benzoyl Fe/S Complexes

SONG Li-Cheng, HU Qing-Mei, CAO Xi-Chuan

Department of Chemistry, Hankai University, Tianjin, 300071

Received:1993-09-25 Revised:1994-01-25 Online:1994-09-24 Published:1994-09-24

Abstract

Abstract: The in situ reactions of the active complex salts [(μ-CO)(μ- RS)Fe₂( CO)₆]^-·Mg⁺Br, formed from triiron dodecacarbonyl, mercaptan or thiophenol and Grignard reagent EtMgBr, with o-or m-chlorobenzoyl chloride in THFat room temperature gave six new substituted μ-benzoyl Fe/Scomplexes with general formulas of(μ-RS) (μ-o-ClC₆ H₄ CO) Fe₂( CO)₆ and( μ- RS)(μ-m-ClC₆ H₄ CO) Fe₂(CO)₆(R=n-Bu, t-Bu, Ph), which were fully characterized by C/Hanalysis, IRand ¹H NMRspectroscopy.

Key words: Synthesis, Structure characterization, Grignard reagent, μ-Benzoyl, Fe/S complex

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SONG Li-Cheng, HU Qing-Mei, CAO Xi-Chuan. Studies on the Readions of Iron Carbonyl-Mercaptan(Thiophenol)-Grignard Reagent System with Benzoyl Chlorides─Syntheses and Structures of Some Substituted μ- Benzoyl Fe/S Complexes[J]. Chem. J. Chinese Universities, 1994, 15(9): 1331.

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Studies on the Readions of Iron Carbonyl-Mercaptan(Thiophenol)-Grignard Reagent System with Benzoyl Chlorides─Syntheses and Structures of Some Substituted μ- Benzoyl Fe/S Complexes

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