Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins(Ⅴ)─Electrocarboxylation of Halobutane with CO2 Catalyzed by CoTPP and VB12

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (7): 956.

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Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins(Ⅴ)─Electrocarboxylation of Halobutane with CO₂ Catalyzed by CoTPP and VB₁₂

ZHENG Guo-Dong¹, YAN Yan¹, GAO Sai², TONG Shan-Ling³, GAO De⁴

1. Department of Chemisiry, Jilin University, Changchun, 130023;
2. Department of Environment Science, Jilin University, Changchun, 130023;
3. Changchun School of Light Industry, Changchun;
4. Department of Chemical Engineering, Hunan University, Changsha

Received:1993-07-15 Revised:1994-01-15 Online:1994-07-24 Published:1994-07-24

Abstract

Abstract: The catalyzation of cobalt etrakis(4-trimethylaniline) porphyrin and vitamine B₁₂for electrocarboxylation of halobutane with CO₂ are studied.The electrocarboxylation in the presence of catalysts can occur at a more positive potential(-1.6Vvs.SCE) than that without catalysts, The products of electrolysis are butyl oxalate(calalyzed by CoTTMAP) and butyl valerate(catalyzed by VB₁₂).The reason of producing different results of electrocarboxylation was researched by means of spectroelectrochemistry.

Key words: Metalloporphyrin, Electrocarboxylation, Vitarnine B₁₂

TrendMD:

ZHENG Guo-Dong, YAN Yan, GAO Sai, TONG Shan-Ling, GAO De. Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins(Ⅴ)─Electrocarboxylation of Halobutane with CO₂ Catalyzed by CoTPP and VB₁₂[J]. Chem. J. Chinese Universities, 1994, 15(7): 956.

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Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins(Ⅴ)─Electrocarboxylation of Halobutane with CO₂ Catalyzed by CoTPP and VB₁₂

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