High Efficient Stationary Phases of HPLC for the Separation of Fullerenes

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (6): 838.

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High Efficient Stationary Phases of HPLC for the Separation of Fullerenes

CHEN De-PU¹, YU Jian-Yuan¹, LIAO Mu-Zhen¹, HUANG He-Sheng², LIU Feng-Ying², LIU Meng-Lin²

1. Dept. of Chem., Tsinghua University, Beijing, 100084;
2. Dept.of Modern Appl.Physics.Tsinghua University, Beijing, 100084

Received:1993-10-25 Revised:1994-02-25 Online:1994-06-24 Published:1994-06-24

Abstract

Abstract: Aseries of high efficient stationary phases of HPLC, FUL-1, FUL-2, FUL-3 and FUL-4, with different separation function groups for the separation of C₆₀and C₇₀were prepared on the basis of analysis of relationship between intermolecular forces and molecular structures.FUL-1, FUL-2 and FUL-3 can be successfully used to separate C₆₀and C₇₀from each other with benzene, toluene and o-xylene as mobile phase, respectively.The action force between FUL-4 and C₆₀or C₇₀is so strong that no solution has been found to elute C₆₀or C₇₀from FUL-4 column, Of all these stationary phases, FUL-3 is the best because of the highest solubilities of Fullerenes in o-xylene and the highest separation factors of Fullerenes in this system.

Key words: Separation of C₆₀and C₇₀, Stationary phase, HPLC

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CHEN De-PU, YU Jian-Yuan, LIAO Mu-Zhen, HUANG He-Sheng, LIU Feng-Ying, LIU Meng-Lin. High Efficient Stationary Phases of HPLC for the Separation of Fullerenes[J]. Chem. J. Chinese Universities, 1994, 15(6): 838.

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High Efficient Stationary Phases of HPLC for the Separation of Fullerenes

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