Effect of iPS-b-iPP Copolymer on Properties and Morphology of iPS/iPP Blends

Abstract

Abstract: The diblock copolymer of isotactic polystyrene and isotactic polypropylene (iPS-b-iPP)was very effective emulsifier for iPS/iPPblend. It was shown that the mechanical properties of iPS-b-iPP/iPS/iPPblend(i.e. lzod impact strength, ultimate elongation and tensile strength at break) dramatically enhanced with the increase of diblock copolymer content. As investigated by DMAand SEM, the characteristic temperature-modulus performance and observed morphology of iPS/iPPblend pair unambiguously supported the interfacial activity of iPS-b-iPPcopolymer as both a dispersant and a "coupling agent". The phase size was significantly reduced, the interfacial adhesion was dramatically increased.

Key words: iPS/iPP blend, Blend, Emulsifier, Styrene-propylene copolymer

TrendMD:

XU Guang-Xue, LIN Shang-An . Effect of iPS-b-iPP Copolymer on Properties and Morphology of iPS/iPP Blends[J]. Chem. J. Chinese Universities, 1994, 15(12): 1856.

[1]	WANG Mingfang, FU Hua, FU Zhibo, WANG Yuerong, ZHANG Hongyang, ZHANG Min, HU Ping. Separation and Characterization of Polymer Blends Using Online Ultra-high Performance Liquid Chromatography-Size Exclusion Chromatography [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210865.
[2]	PU Yangyang, NING Cong, LU Yao, LIU Lili, LI Na, HU Zhaoxia, CHEN Shouwen. Preparation and Characterizations of Cross-linked Sulfonated Poly（ether ether ketone）/Partially Fluorinated Sulfonated Poly（aryl ether sulfone） Blend Membranes [J]. Chem. J. Chinese Universities, 2021, 42(6): 2002.
[3]	HUANG Huilong, HUANG Hanxiong. Low-temperature Impact Behavior of Droplet on Injection-compression Molded Nanostructured PP/POE Blend Surfaces [J]. Chem. J. Chinese Universities, 2021, 42(10): 3195.
[4]	FANG Mingliang,LIU Dong,HU Meishao,WANG Lei. Synthesis and Properties of Highly Branched Comb-shaped Poly(aryl ether sulfone)s/imidazolium-functionalized Graphene Oxide Anion Exchange Composite Membranes ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 365.
[5]	LI Haocheng, GAO Yuan, XIN Yingchun, ZONG Hua, LIU Huiying, ZHANG Lei, ZHANG Lu. Interfacial Dilational Rheology of Polyether Demulsifiers [J]. Chem. J. Chinese Universities, 2019, 40(4): 809.
[6]	LIU Zihao,XIAO Han,YAO Yuan,WANG Ting,WU Liguang,ZHANG Xueyang. Fabrication of PVDF Hybrid Blending Membrane via Microemulsion Polymerization Coupling with Blending Method ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2248.
[7]	REN Huicheng,WU Yingfei,LIU Dandan,NIE Huarong,HE Aihua. Crystallization, Nucleation and Kinetics of TPI in SSBR/TPI Blends^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 1091.
[8]	YE Lishaya, HUANG Yajiang, KONG Miqiu, LOU Fangli, YANG Qi, LI Guangxian. Effect of Amphiphilic Silica Rods on the Morphology of Immiscible Polyisobutylene/Polydimethylsiloxane Blends Under Simple Shear Flow [J]. Chem. J. Chinese Universities, 2017, 38(8): 1470.
[9]	WANG Hao, ZHANG Jianping, MA Yunsheng, WANG Riguo, HE Aihua. Modification of SSBR/BR with Trans-1,4-Polyisoprene Alloy Rubber for High Performance Passenger Car Radical Tire Tread Stock^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2095.
[10]	LEI Bei, LUO Hui, SHI Mengke, ZHANG Xi. Structure and Properties of Starch/Poly(butylene succinate) Blends Plasticized by [BMIM]Cl^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1722.
[11]	TAO Yingyong, ZHANG Xulue, HU Zhaoxia, ZHANG Jingjing, GENG Hui, GAO Ying, YUAN Zufeng, BI Huiping, CHEN Shouwen, WANG Lianjun. Preparation and Properties of Blend Proton Exchange Membranes Based on Side-chain Type Fluorine-containing Sulfonated Poly(ether sulfone) and Sulfonated Polyimide^† [J]. Chem. J. Chinese Universities, 2016, 37(4): 793.
[12]	YAO Kuncheng, NIE Huarong, MA Yunsheng, WANG Riguo, WANG Xiaojian, HE Aihua. Crystallization Kinetics of trans-/cis-Polyisoprene Blends^† [J]. Chem. J. Chinese Universities, 2016, 37(12): 2315.
[13]	LIU Ruiqing, LIANG Shuang, JIANG Cun, XU Zushun, XU Haibo. Synthesis and Proporties of Temperature and pH-sensitive and Gadolinium Contained Polymeric Magnetic Resonance Imaging Contrast Agent^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 155.
[14]	LIU Dongmei, DAI Lijun, DUAN Xiaozheng, SHI Tongfei, ZHANG Hanzhuang. Monte Carlo Simulation of Interfacial Properties in Homopolymer/Diblock Copolymer/Homopolymer Ternary Polymer Blends^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1752.
[15]	XIONG Zhuoyue, ZHANG Boyuan, WANG Weijia, GUO Zhaoxia, YU Jian. Electrical Percolation Model of Ternary Carbon Filler Mixture in Polymer Blends^† [J]. Chem. J. Chinese Universities, 2015, 36(8): 1641.

Effect of iPS-b-iPP Copolymer on Properties and Morphology of iPS/iPP Blends

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments