Synthesis, Crystal Structure and Thermal Decomposition of[Cu(NBOCTB)](ClO4)2·2DMF

Abstract

Abstract: The complex of Cu(Ⅱ)with N, N, N'N'-tetra[1'-benzyl-2'-benzimidazol)methyl]-trans^-1, 2-diaminocyclohexane(NBOCTB), [Cu(NBOCTB)](ClO₄)₂·2DMF, wasprepared. The crystal of the complex belongs to triclinic system and P₁ space group with a=1.1851(5)nm, b=1.2255(3)nm, c=2.5237(5)nm;a=92.37(2)°, β=98.01(2)°, γ=107.82(3)°;V=3.442(4)nm3, M=1043.93, Z=2, D_x=1.36g/cm³, μ=4.60 cm^-1, F(000)=1470. The thermal decompostion of the complex was studied by TG-DTGtechniques.The process of the decomposition can be divided into four stages:(19941106-1597-1.jpg)

Key words: Copper complex, Crystal structure, Thermal decomposition

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Ll Xiao-Yan. Synthesis, Crystal Structure and Thermal Decomposition of[Cu(NBOCTB)](ClO₄)₂·2DMF[J]. Chem. J. Chinese Universities, 1994, 15(11): 1597.

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Synthesis, Crystal Structure and Thermal Decomposition of[Cu(NBOCTB)](ClO₄)₂·2DMF

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