Study of Copper Electrodeposition on HOPG by in Situ Electrochemical Scanning Tunneling Microscope with Atomic Resolution

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (5): 706.

• Articles • Previous Articles Next Articles

Study of Copper Electrodeposition on HOPG by in Situ Electrochemical Scanning Tunneling Microscope with Atomic Resolution

LI Chun-Zeng, XIE Zhao-Xiong, MAO Bing-Wei, ZHUO Xiang-Dong, MU Ji-Qian, YE Jian-Hui, FENG Zu-De, TIAN Zhao-Wu

Deft, of Chem., Slate Key Lab.for Physical Chem.of the Solid Surface, Xiamen Univ., Xiamen, 361005

Received:1992-11-19 Online:1993-05-24 Published:1993-05-24

Abstract

Abstract: Ahome-built in situ electrochemical scanning tunneling microscope (ECSTM) was applied to investigation of the electrodeposition of Cu on HOPGin CuSO₄ solution under potential control.During potential cycling, the deposition and dissolution processes of Cu were clearly observed.At about-250 mV(vs.Cu²⁺/Cu) it was found that the STMimages changed with time.Aregular hexagonal lattice was observed first, with a next-neighbour atomic distance of 0.40±0.02 nm, which is considered to be HOPG(0001)-(√3×√3)R30° Cu adlattice.Following that, Cu(111) and Cu(110) faces appeared, both showing long range-corrugation patterns.

Key words: ECSTM, Atomic resolution, Cu, Electrodeposition, Adlattice

TrendMD:

LI Chun-Zeng, XIE Zhao-Xiong, MAO Bing-Wei, ZHUO Xiang-Dong, MU Ji-Qian, YE Jian-Hui, FENG Zu-De, TIAN Zhao-Wu . Study of Copper Electrodeposition on HOPG by in Situ Electrochemical Scanning Tunneling Microscope with Atomic Resolution[J]. Chem. J. Chinese Universities, 1993, 14(5): 706.

[1]	HUAN Xinyu, LAI Ganqiang, HUANG Yue, YANG Caiguang. Research Progress on Chemical Intervention of N⁶-methyladenosine Modification [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220340.
[2]	GE Yicong, NIE Wanli, SUN Guofeng, CHEN Jiaxuan, TIAN Chong. Silver-catalyzed ［5+1］ Cyclization of 2-Vinylanilines with Benzisoxazoles [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220142.
[3]	WANG Xuebin, XUE Yuan, MAO Hua’nyu, XIANG Yanxin, BAO Chunyan. Preparation of Photo/reduction Dual-responsive Hydrogel Microspheres and Their Application in Three-dimensional Cell Culture [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220116.
[4]	WENG Meiqi, SHANG Guiming, WANG Jiatai, LI Shenghua, FAN Zhi, LIN Song, GUO Minjie. Template Simulation of Organophosphorus Nerve Agent Molecularly Imprinted Polymers [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220136.
[5]	ZHANG Zhicai, WANG Yuge, GU Qianqian, LYU Yongpeng, XIAO Jianshu, YIN Yuan, SUN Hongguo, ZHENG Yafang, SUN Zhaoyan. Flocculation of Fillers in Isoprene Rubber and Its Effects on Properties [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220155.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	QIU Liqi, YAO Xiangyang, HE Liangnian. Visible-light-driven Selective Reduction of Carbon Dioxide Catalyzed by Earth-abundant Metalloporphyrin Complexes [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220064.
[8]	WANG Zhengwen, GAO Fengxiang, CAO Han, LIU Shunjie, WANG Xianhong, WANG Fosong. Synthesis and Property of CO₂ Copolymer⁃based UV-curable Polymer [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220236.
[9]	DAI Wei, HOU Hua, WANG Baoshan. Theoretical Investigations on the Electronic Structures and Reactivity of Heptafluoro-iso-butyronitrile Anion [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220044.
[10]	LIN Zhongqiao, CHEN Peipei, WANG Lei. Application of Mineralocorticoid Receptor Antagonists with Different Chemical Structures in Cardiovascular Diseases [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220059.
[11]	GAO Zhiwei, LI Junwei, SHI Sai, FU Qiang, JIA Junru, AN Hailong. Analysis of Gating Characteristics of TRPM8 Channel Based on Molecular Dynamics [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220080.
[12]	JI Fa, LIU Ling, YU Linling, SUN Yan. Effects of Muco-inert and Acid-sensitive Modification on Mucosal Penetration of Nanoparticles [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210837.
[13]	LI Zhiguang, QI Guodong, XU Jun, DENG Feng. Role of Catalyst Acidity in Glucose Conversion over Sn-Al-β Zeolite as Studied by Solid-state NMR [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220138.
[14]	SONG Youwei, AN Jiangwei, WANG Zheng, WANG Xuhui, QUAN Yanhong, REN Jun, ZHAO Jinxian. Effects of Ag，Zn，Pd-doping on Catalytic Performance of Copper Catalyst for Selective Hydrogenation of Dimethyl Oxalate [J]. Chem. J. Chinese Universities, 2022, 43(6): 20210842.
[15]	ZENG Xianyang, ZHAO Xi, HUANG Xuri. Mechanism of Inhibition of Glucose and Proton Cotransport Protein GlcPSe by Cytochalasin B [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210822.

Study of Copper Electrodeposition on HOPG by in Situ Electrochemical Scanning Tunneling Microscope with Atomic Resolution

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments