Studies on Structure and Porperties of Tetraphenylporphyrin and Its Derivatives (Ⅲ)——Standard Molar Enthalpies of Sublimation, and Formation, Enthalpies of Strain and Resonance Energy

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (4): 509.

• Articles • Previous Articles Next Articles

Studies on Structure and Porperties of Tetraphenylporphyrin and Its Derivatives (Ⅲ)——Standard Molar Enthalpies of Sublimation, and Formation, Enthalpies of Strain and Resonance Energy

LI Liang-chao¹, LUO Ming-dao², QU Song-sheng², HUANG Su-qiu², YAN Xiao-ci²

1. Jingzhon Education College, Jingzhou, 434100;
2. Department of Chemistry, Wuhan University, Wuhan, 430072

Received:1991-04-19 Online:1992-04-24 Published:1992-04-24

Abstract

Abstract: Based upon the structural characteristics of tetraphenylporphyrin and its derivatives, we defined Firstly, (这里有图片19920428-509-1.gif) and Δ_S-R Phy-X are determined, then the standard molar enthalpies of sublimation, the standard enthalpies of formation in gas phase are obtained.The enthalpies of strain, resonance energies and twisty angle of these compounds are also obtained by HMO method.The linear relationship between the gas phase standard enthalpies of formation and the substituent constants is discussed.

Key words: Strain effect, Resonance effect, Twisty angle, Resonance energy

TrendMD:

LI Liang-chao, LUO Ming-dao, QU Song-sheng, HUANG Su-qiu, YAN Xiao-ci. Studies on Structure and Porperties of Tetraphenylporphyrin and Its Derivatives (Ⅲ)——Standard Molar Enthalpies of Sublimation, and Formation, Enthalpies of Strain and Resonance Energy[J]. Chem. J. Chinese Universities, 1992, 13(4): 509.

[1]	WANG Mengyu, CAO Simin, LI Haoyang, ZHANG Mengjie, LI Dong, ZHAO Zenan, XU Jianhua. Fluorescence Resonance Energy Transfer Between Coenzyme NADH and Tryptophan [J]. Chem. J. Chinese Universities, 2020, 41(11): 2473.
[2]	FENG Wei,WANG Bowei,JIANG Yang,LI Longyun. Design, Preparation and Surface-enhanced Raman Scattering(SERS) Spectrum of Single Ag Nanodot^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1345.
[3]	LIANG Donglei, SONG Qiusheng, YAO Yutian, LIU Ben. Preparation of Complex Nanogel with Up-conversion Fluorescence-responsive Performance and Its Fluorescence Energy Transfer Behavior^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 583.
[4]	LIU Huiqiang, PENG Chao, CHEN Ning, LIU Yangping. Novel Fluorescent/EPR Difunctional Probe for Detecting Hypochlorite^† [J]. Chem. J. Chinese Universities, 2017, 38(9): 1542.
[5]	CHEN Jiayi, SU Wei, WANG Enju. Highly Selective Ratiometric Fluorescent Probe for Hg²⁺Based on Fluorescence Resonance Energy Transfer Between 1,8-Naphthalimide and Rhodamine B^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 232.
[6]	ZHANG Xiafei, CHENG Rui, SHI Zhilu, JIN Yan. Label-free Fluorescence Assay of Telomerase RNA Based on Strand Displacement Amplification^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 12.
[7]	MA Lina, LIU Fuyao, GAO Jiaxue, WANG Zhenxin. Polydopamine Nanoparticle-based Fluorescence Resonance Energy Transfer Assay for microRNA Detection^† [J]. Chem. J. Chinese Universities, 2015, 36(6): 1061.
[8]	HUANG Yan-Qin, QIN Wei-Sheng, REN Hou-Ji, CAO Guo-Yi, LIU Xing-Fen, HUANG Wei. Novel Adenosine Detection Method Based on Cationic Conjugated Polymer and Aptamer [J]. Chem. J. Chinese Universities, 2012, 33(10): 2213.
[9]	LIANG Xue-Ying, LIU Qiong, CHEN Ping, HUO Ke-Ke, HU Tian-Yong, NI Jia-Zuan. Screen and Verification of Interactive Protein of Selenoprotein K in Human Liver [J]. Chem. J. Chinese Universities, 2012, 33(02): 313.
[10]	FENG Wei, ZHAO Guang-Yao, SUN Ling-Dong, YAN Chun-Hua*. Luminescence Resonance Energy Transfer in Au@SiO2/LaF3∶Ce, Tb Nanostructures [J]. Chem. J. Chinese Universities, 2011, 32(3): 635.
[11]	ZHANG Xiao-Ping, HUANG Yan-Qin, FAN Chun-Hai, HUANG Wei. Novel Method of Phosphatase Detection Based on Cationic Conjugated Polymer and Enzymatic Substrate Probe [J]. Chem. J. Chinese Universities, 2011, 32(11): 2548.
[12]	WANG Xu-Yan, LIANG Jian-Gong, MA Jin-Jie, CHEN Shu-Han, HAN He-You*. Construction and Application of CdTe Quantum Dots-Rhodamine 6G Fluorescence Resonance Energy Transfer Systems [J]. Chem. J. Chinese Universities, 2010, 31(2): 260.
[13]	Ablikim Kerim^*, CHEN Jia-Li, Ablimit Abdukadir. Debate on the Aromaticity of Boron- or Nitrogen-Doped Fullerene C₂₀ [J]. Chem. J. Chinese Universities, 2008, 29(9): 1810.
[14]	FEI Yan-Qun¹, LUO Gui-Min¹, FENG Guo-Dong², FEI Qiang², CHEN Huan-Wen², LIANG Xue-Kai², ZHAO Xiao-Jun³, HUAN Yan-Fu^1,2. Synthesis of Fluorescent Nanoparticle Sensors for Simultaneous Determination of Double Targets [J]. Chem. J. Chinese Universities, 2008, 29(1): 83.
[15]	ZHANG Ji-Mei¹, DAI Zhao¹, GUO Ning¹, XU Shi-Chao¹, DONG Quan-Xi¹, SUN Bo². Fluorescence Resonance Energy Transfer Between CdTe Quantum Dot Donors and Au Nanoparticles Labeled DNA Acceptors [J]. Chem. J. Chinese Universities, 2007, 28(2): 254.

Studies on Structure and Porperties of Tetraphenylporphyrin and Its Derivatives (Ⅲ)——Standard Molar Enthalpies of Sublimation, and Formation, Enthalpies of Strain and Resonance Energy

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments