Studies on the Complexes of Rare Earth with Organic Ligands Containing Sulphur Atoms (Ⅷ)——Synthesis and Properties of Poly nuclear Complexes of Rare Earth Acetates with Nickel Glycinemethanedithioate

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (2): 141.

• Articles • Next Articles

Studies on the Complexes of Rare Earth with Organic Ligands Containing Sulphur Atoms (Ⅷ)——Synthesis and Properties of Poly nuclear Complexes of Rare Earth Acetates with Nickel Glycinemethanedithioate

TANG Ning¹, CAN Xin-min¹, ZHANG Wei-guang¹, SUN Fu-yan¹, TAN Min-yu¹, JIANG Zhi-cheng²

1. Depart, of Chem., Lanzhou University, Lanzhou, 730000;
2. Lanzhou Institute of Chemical Physics, Academia Sinica

Received:1991-02-05 Online:1992-02-24 Published:1992-02-24

Abstract

Abstract: The new polynuclear complexes of rare earth acetates with nickel gly-cinemethanedithioate were synthesized in the aqueous alcohol solution and characterized by elemental analysis, solubility, infrared spectra, X-ray photoelectron spectroscopy and ¹H NMRThe results show that the composition of the complexes are RENi(Gc)₂Ac·H₂O(RE = La-Gd, except Ce, Pm; Gc=glycinemethanedithioate) and RE₂[Ni(Gc)₂]₃·xH₂O(RE = Tb-Lu, Y; x = 4,8,10).

Key words: Rare earth, Glycinemethanedithioate, Polynuclear complex, Synthesis, Property

TrendMD:

TANG Ning, CAN Xin-min, ZHANG Wei-guang, SUN Fu-yan, TAN Min-yu, JIANG Zhi-cheng. Studies on the Complexes of Rare Earth with Organic Ligands Containing Sulphur Atoms (Ⅷ)——Synthesis and Properties of Poly nuclear Complexes of Rare Earth Acetates with Nickel Glycinemethanedithioate[J]. Chem. J. Chinese Universities, 1992, 13(2): 141.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[3]	TENG Zhenyuan, ZHANG Qitao, SU Chenliang. Charge Separation and Surface Reaction Mechanisms for Polymeric Single-atom Photocatalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220325.
[4]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[5]	LUO Xinyan, JIA Ruonan, XIANG Yong, ZHANG Xiaokun. Progress on the Stretchable Composite Solid Polymer Electrolytes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220149.
[6]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[7]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[8]	GAO Jian, FENG Yiyu, FANG Wenyu, WANG Hui, GE Jing, FENG Wei. Alkane Grafted Phase Change Azobenzene Materials Based on Low Temperature Heat Release [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220146.
[9]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[10]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[11]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[12]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[13]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[14]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[15]	LI Qiao, ZHAO Yang, WANG Enju. Moisture Absorption Reaction and Fluorescence Property of Highly Active Michael System Based on Arylidenemalononitrile [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210690.

Studies on the Complexes of Rare Earth with Organic Ligands Containing Sulphur Atoms (Ⅷ)——Synthesis and Properties of Poly nuclear Complexes of Rare Earth Acetates with Nickel Glycinemethanedithioate

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments