Studies on the Synthesis, Structure and Properties of Cluster [Fe(DMF)6][W2S6]

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (12): 1582.

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Studies on the Synthesis, Structure and Properties of Cluster [Fe(DMF)₆][W₂S₆]

ZHANG Zhi-Gui¹, WANG Tao¹, NIU Shu-Yun¹, DONG Wei-Tong¹, FAN Yu-Guo²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Institute of Theoretical Chemistry, Jilin University, Changchun

Received:1991-12-19 Revised:1992-10-14 Online:1992-12-24 Published:1992-12-24

Abstract

Abstract: A novel cluster [Fe(DMF)₆][W₂S₆] was prepared by using(NH₄)₂WS₄,FeCl₃ and NaS₂CNC₅H₁₀ as the reaction materials.Its structure was determined by X-ray method.The parameters of the crystal cell for the compound are a=0.8778(1)nm,b=0.9467(3)nm,c=l.1362(6)nm,α=71.506(1)°o,β=74.775(2)°,γ=74.775(2)°,V=0.84806 nm³ and Z=1.The structure was refined by block-diagonal matrix least square method,and the final agreement factor is R=0.0811.Moreover,the infrared spectra and UV-Visible spectra were measured.

Key words: Cluster, [Fe(DMF)₆][W₂S₆], Structure and properties

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ZHANG Zhi-Gui, WANG Tao, NIU Shu-Yun, DONG Wei-Tong, FAN Yu-Guo. Studies on the Synthesis, Structure and Properties of Cluster [Fe(DMF)₆][W₂S₆][J]. Chem. J. Chinese Universities, 1992, 13(12): 1582.

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Studies on the Synthesis, Structure and Properties of Cluster [Fe(DMF)₆][W₂S₆]

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