Sytheses, Structure and SAR Study on New Sulfonylurea Compounds(Ⅰ)——Crystal and Molecular Structure of N-(2'-pyrimidinyl)-2-ethyl Carboxylate-benzene Sulfonyl urea

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1411.

• Articles • Previous Articles Next Articles

Sytheses, Structure and SAR Study on New Sulfonylurea Compounds(Ⅰ)——Crystal and Molecular Structure of N-(2'-pyrimidinyl)-2-ethyl Carboxylate-benzene Sulfonyl urea

LI Zheng-Ming¹, JIA Guo-Feng¹, WANG Ling-Xiu¹, LAI Cheng-Ming², WANG Ru-Ji³, WANG Hong-Gen³

1. National Key laboratory of Elemento-Organic Chemistry, Elemento-Organk Chemistry Institute, Nankai University, Tianjin, 300071;
2. Department of Chemistry, Nankai University;
3. Central Laboratory of Nankai University

Received:1992-03-03 Revised:1992-06-20 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: Synthesis and crystal structure of title molecule was reported here.The crystal is monoclinic,belonging to space group P2₁/a with unit cell parameter a=0.7384(2)nm,b=2.1496(4)nm,c=0.9973(2)nm,β=90.12(2)°,V=1.576 nm³,Z=4,R=0.059 for 1421 reflections.Molecular structure was discussed.There are three different planes in molecule,in each of which a conjugated system was formed.The empty 3_dxz orbital of atom Senters the formation of conjugated bond.The intra-molecule hydrogen bond between atom Nand Hwas found.

Key words: Crystal structure, Molecular structure, New sulfonylurea compound

TrendMD:

LI Zheng-Ming, JIA Guo-Feng, WANG Ling-Xiu, LAI Cheng-Ming, WANG Ru-Ji, WANG Hong-Gen. Sytheses, Structure and SAR Study on New Sulfonylurea Compounds(Ⅰ)——Crystal and Molecular Structure of N-(2'-pyrimidinyl)-2-ethyl Carboxylate-benzene Sulfonyl urea[J]. Chem. J. Chinese Universities, 1992, 13(11): 1411.

References

Related Articles 15

[1]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[2]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[3]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[4]	TIAN Xia,YANG Fuqun,YUAN Wei,ZHAO Lei,YAO Lei,ZHEN Xiaoli,HAN Jianrong,LIU Shouxin. Synthesis, Structure and Recognition Properties of Macrocyclic Crown Ethers with Oxadiazole ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 490.
[5]	LIU Dongmei,SU Yajing,LI Shanshan,XU Qiwei,LI Xia. Transition Metal Coordination Polymers Constructed by 4-(4-Carboxyphenoxy)isophthalic Acid: Synthesis, Crystal Structure, Fluorescence Sensing and Photocatalysis ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 253.
[6]	QIN Liulei,LIU Yang,GUAN Xiaoqin,ZHENG Xiaoyuan,ZHANG Ziyu,LIU Zunqi. Synthesis and Switchable Dielectric Properties of an Inorganic-organic Hybrid Complex [H₂(DABCO)CuCl₄]·H₂O ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 70.
[7]	LIU Shasha, WANG Lin, YUAN Shiling, CAO Xiaorong. Molecular Dynamics Simulation of Different Configurations of PAO Molecules in Shear Iron Plates^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1472.
[8]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[9]	WANG Dongmei,LIU Zihua,LI Guanghua,LIU Yunling,LI Chunxia. Synthesis, Structure and Fluorescent Property of Indium-based Bimetallic Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1886.
[10]	TIAN Huan, ZHANG Menglong, WANG Lisha, TONG Bihai, ZHAO Zhuo. Synthesis of 4,13-Dithio Benzene and-18-Crown-6 and Its Selective Extractability on A $g + †$ [J]. Chem. J. Chinese Universities, 2018, 39(6): 1191.
[11]	ZHU Lei,HAN Junyan,CHANG Haizhen,QIU Yuyuan,ZHANG Yanan,PENG Danni,HU Wei,MIAO Shaobin. Different Pathways for the Cyclocondensation Reactions of 1,2-Diamine and 1,2-Diketone^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2686.
[12]	LI Zheng, LI Rui, LI Xia. Synthesis, Crystal Structure and Fluorescent Properties of Transition Metal Complexes Constructed with 2-(3'-Carboxyphenoxy)benzoic Acid and N-Donor Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2363.
[13]	CHEN Qidan, TANG Junjie, FANG Qianrong. Highly Stable Fluorine Containing Hierarchical Porous Covalent Organic Framework^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2357.
[14]	YUN Jixing,HU Zhili,LI Yumeng,JIN Jing,CHEN Chong,YAN Xin,LIU Yonghua,DING Yu,CHI Yuxian,NIU Shuyun. Synthesis, Structure and Photoelectric Property of A Series of Ni(Ⅱ) Complexes Constructed Through Aromatic Carboxylic Ligands^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2161.
[15]	TAN Ying, XIAO Mengwu, YE Jiao, HU Aixi, ZENG Ziqing, OU Xiaoming. Synthesis, Crystal Structure and Fungicidal Activity of (Z)-3,3-Dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-one O-[(5-Aryl-1,3,4-oxadiazol-2-yl)methyl] oxime [J]. Chem. J. Chinese Universities, 2017, 38(8): 1375.

Sytheses, Structure and SAR Study on New Sulfonylurea Compounds(Ⅰ)——Crystal and Molecular Structure of N-(2'-pyrimidinyl)-2-ethyl Carboxylate-benzene Sulfonyl urea

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments