Synthesis and Conductivity of Organometallic Solids [Fe(CpMe)2][M(dmit)2] and [FeCp(Tol)]n[M(dmit)2]

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1398.

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Synthesis and Conductivity of Organometallic Solids [Fe(CpMe)₂][M(dmit)₂] and [FeCp(Tol)]n[M(dmit)₂]

QIN Jin-Gui, ZHOU Wei-Hua, DING Yong-Pmg, LIU Dao-Yu

Department of Chemistry, Wuhan University, Wuhan, 430072

Received:1991-12-28 Revised:1991-08-17 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: Six new organometallic radical ionic salts,[Fe(CpMe)₂][M(dmit)₂] and [FeCp(Tol)]_n[M(dmit)₂]_n(M=Ni,Pd,Pt,Cu or Co;CpMe=methylcyclopentadienyl;Tol=toluene;H₂dmit=4,5-dimercapto-1,3-dithiole-2-thione;n=1 or 2)were synthesized,and characterized by elemental analysis,infrared and mass spectroscopy.The electrical conductivity of solid state was reported and discussed in terms of structure-property relationship.

Key words: Organometailic compounds, Radical ionic salts, Dmit, Synthesis, Conductivity

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QIN Jin-Gui, ZHOU Wei-Hua, DING Yong-Pmg, LIU Dao-Yu. Synthesis and Conductivity of Organometallic Solids [Fe(CpMe)₂][M(dmit)₂] and [FeCp(Tol)]n[M(dmit)₂][J]. Chem. J. Chinese Universities, 1992, 13(11): 1398.

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Synthesis and Conductivity of Organometallic Solids [Fe(CpMe)₂][M(dmit)₂] and [FeCp(Tol)]n[M(dmit)₂]

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