The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (9): 1160.

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The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616

Wang Er-kang, Wu Ya-ying, Qi De-yao, Yu Ze-mu

Laboratory of Electroanatytical Chemistry, Changchun Institute ofApplied Chemistry, Chinese Academy of Sciences, Changchun, 130022

Received:1990-12-01 Online:1991-09-24 Published:1991-09-24

Abstract

Abstract: The proton transfer across the water/ nitrobenzene interface facilitated by ionophore ETH1616(N,N-bis heptyl-ethyldiamide) has been investigated by chronopotentiometry with linear current scanning and cyclic voltammetry. The stability constant of the complex and the diffusion coefficient of ionophore ETH1616in the nitrobenzene phase have been estimated, respectively. The mechanism of the proton transfer has been discussed.

Key words: Neutral ionophore, Water/oil interface, N,N-bis-heptyl-ethyldiamide, Proton transfer

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Wang Er-kang, Wu Ya-ying, Qi De-yao, Yu Ze-mu. The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616[J]. Chem. J. Chinese Universities, 1991, 12(9): 1160.

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The Proton Transfer Across Water/Oil Interface Facilitatited by Neutral lonophore ETH1616

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