Studies on Spectroelectrochemistry (Ⅲ)--The Oxidation Behaviour of Diethylstilbestrol and the Rearrangement of Electrode Reaction Product on an Optical Thin Layer Gold Minigrid Electrode

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (8): 1119.

• Articles • Previous Articles Next Articles

Studies on Spectroelectrochemistry (Ⅲ)--The Oxidation Behaviour of Diethylstilbestrol and the Rearrangement of Electrode Reaction Product on an Optical Thin Layer Gold Minigrid Electrode

Deng Jia-qi, Deng Zi-feng, Wu Xing-liang

Department of Chemistry, Fudan University, Shanghai, 200433

Received:1990-03-06 Online:1991-08-24 Published:1991-08-24

Abstract

Abstract: In methanol-Britton Robinson Buffer-sodium chloride solution and in the presence of ferro-cence as a catalyst, the electrochemical oxidation of diethylstilbestrol was investigated by the thin layer spectroelectrochemical method at an optical gold minigrid electrode. It is found that diethylstilbestrol is electrooxidized to 4,4'-diethylstilbestrol quinone, then the latter rearranges to Z,Z-dienestrol. The rearrangement rate constant over the range of pH from 6 to 8 was measured by single potential-step chronoabsorptometry.

Key words: Spectroelectrochemistry, Single potential-step chronoabsorptometry, Diethylstilbestrol

TrendMD:

Deng Jia-qi, Deng Zi-feng, Wu Xing-liang . Studies on Spectroelectrochemistry (Ⅲ)--The Oxidation Behaviour of Diethylstilbestrol and the Rearrangement of Electrode Reaction Product on an Optical Thin Layer Gold Minigrid Electrode[J]. Chem. J. Chinese Universities, 1991, 12(8): 1119.

[1]	FAN Hui, JIN Baokang. Investigation on Electrochemical Capture of CO₂ by Quinone Derivatives Based on in situ FTIR Spectroelectrochemistry ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1847.
[2]	QIAO Xuejiao, LI Dan, CHENG Longjiu, JIN Baokang. Mechanism of Electrochemical Capture of CO₂ via Redox Cycle of 2-Amino-3-chloro-1,4-naphthoquinone in BMIMBF₄ [J]. Chem. J. Chinese Universities, 2019, 40(8): 1606.
[3]	ZHU Yun,LI Dan,JIN Baokang. Study on Redox Mechanism of 2-Methyl-naphthoquinonein Dimethyl Sulfoxide and Acetonitrile^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 2025.
[4]	LI Yuying, LI Dan, CHENG Longjiu, JIN Baokang. Investigation on Redox Mechanism of p-Nitrophenol in Aprotic Media^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2023.
[5]	LI Tong, JIN Baokang. Electrochemical Redox of Benzoquinone in Ionic Liquids^† [J]. Chem. J. Chinese Universities, 2014, 35(4): 847.
[6]	LI Dan, JIN Bao-Kang. Study on the Electrochemical Redox Mechanism of 2-Hydroxy-1,4-naphthoquinone [J]. Chem. J. Chinese Universities, 2013, 34(8): 1959.
[7]	OU Zhong-Ping, ZHU Jia-Li, LIN Wen-Sheng, FANG Yuan-Yuan, LU Gui-Fen. Synthesis, Electrochemical and Spectral Properties of Novel meso-Chlorophenyl Substituted Free-base Corroles [J]. Chem. J. Chinese Universities, 2012, 33(06): 1130.
[8]	JIANG Xiu-E, ZHANG Zhe-Ling, HUANG Wei-Min, LIU Xiao-Qiang, WANG Er-Kang, DONG Shao-Jun. In-situ UV and CD Spectroelectrochemistry Investigation of the Electrochemical Reduction Reaction Inducing Conformational Transition of Microperoxidase-11 [J]. Chem. J. Chinese Universities, 2005, 26(2): 321.
[9]	CHENG Gui-Fang, ZHANG Dong-Mei, DING Min, QU Hai-Yun, HE Pin-Gang, FANG Yu-Zhi . Studies on the Interaction of Daunomycin and the Specific Sequence of DNA [J]. Chem. J. Chinese Universities, 2003, 24(8): 1395.
[10]	JIAO Kui, Gang, YANG Tao, WU Jun-Feng . Electrochemical and Spectroelectrochemical Study of m-Phenylenediamine [J]. Chem. J. Chinese Universities, 2003, 24(6): 1005.
[11]	QU HaiYun, CHENG GuiFang, PENG HuiQi, HE PinGang, FANG YuZhi . Spectroelectrochemistry Studies of Antitumor Antibiotics Daunomycin [J]. Chem. J. Chinese Universities, 2001, 22(12): 2000.
[12]	WANG Zhen-Xin, LIU Dian-Jun, LIN Xiang-Qin. A Mechanistic Study of Electrochemical Oxidation Processes of (OEP)Mg(Ⅱ) in the Presence of Anions [J]. Chem. J. Chinese Universities, 1999, 20(9): 1442.
[13]	YANG Chen, YU Jun-Sheng, ZHOU Tao-Yu, FANG Hui-Qun . Design and Characterization of a Versatile, Thin-layer Spectroelectrochemistry Cell [J]. Chem. J. Chinese Universities, 1999, 20(8): 1205.
[14]	FENG Min, HE Pin-Gang, YANG Yu-Lin, FANG Yu-Zhi . Studies on Spectroelectrochemistry of Adriamycin [J]. Chem. J. Chinese Universities, 1999, 20(6): 866.
[15]	YE Bao-Xian, FANG Cheng, ZHOU Xing-Yao . Spectroelectrochemical Study of Hemoglobin at Bare Silver Electrodes [J]. Chem. J. Chinese Universities, 1998, 19(9): 1405.

Studies on Spectroelectrochemistry (Ⅲ)--The Oxidation Behaviour of Diethylstilbestrol and the Rearrangement of Electrode Reaction Product on an Optical Thin Layer Gold Minigrid Electrode

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments