Characterization and Structure of Complex of Cadmium with 2-[(o-Hydroxybenzylidene)amino]phenol and Pyridine

Abstract

Abstract: Acomplex of cadmium with 2-[(o-hydroxybenzylidene) amino] phenol (H₂Sap) and pyri-dine Cd₂(C₁₃H₉NO₂)₂(C₅H₅)₆was prepared. Its structure was determined. It is found that the crystal belongs to the monoclinic system with space group P2₁/c, and the unit cell parameters are:a=14. 006(3)Å, b=10. 362(1)Å, c=18. 435(2)Å,β=111.29(1)°,V=2492. 77Å³M=1121.86, Z=2, D_I=1.495g/cm³, μ=9. 023 cm^-1, F(000)=1136.The cadmium coordination configuration is octahedral. The properties of the complex have been characterized by IR, NMR, DTA and TGtechniques.

Key words: Cadmium, Coordination compound, Properties, Structure

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Liu De-xin, Cui Xue-gui, Hao Shu-xuan, Li Feng-ling . Characterization and Structure of Complex of Cadmium with 2-[(o-Hydroxybenzylidene)amino]phenol and Pyridine[J]. Chem. J. Chinese Universities, 1991, 12(2): 165.

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Characterization and Structure of Complex of Cadmium with 2-[(o-Hydroxybenzylidene)amino]phenol and Pyridine

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