The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (10): 1373.

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The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure

Wu Tong-hao, Li Jian-qing, Yang Hong-mao, Wang Guo-jia, Zhang Heng-bin, Wei Quan, Jiang Yu-zi

Department of Chemistry, Jintin University, Changchun, 130023

Received:1990-06-26 Online:1991-10-24 Published:1991-10-24

Abstract

Abstract: The molybdophosphoric acid with Dawson structure and its tetrabutylammonium, tetrabutylphosphorium salts were synthesized. Their purities were checked by IR, ³¹PNMR and cyclic voltammetry, and their thermal stabilities, acidities and redox properties were also studied. The results ' show that the molybdophosphoric acid with Dawson structure should have stronger oxidizability than that with of the acid Keggin one.

Key words: Molybdophosphoric acid with Dawson structure, IR spectra, Characterization

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Wu Tong-hao, Li Jian-qing, Yang Hong-mao, Wang Guo-jia, Zhang Heng-bin, Wei Quan, Jiang Yu-zi . The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure[J]. Chem. J. Chinese Universities, 1991, 12(10): 1373.

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The Synthesis and Characterization of Molybdophosphoric Acid with Dawson Structure

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