Spectral Performance and Fluorescence Detection of Ionic Liquid [MBPy]Tf2N†

doi:10.7503/cjcu20150242

Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (10): 1906.doi: 10.7503/cjcu20150242

• Analytical Chemistry • Previous Articles Next Articles

Spectral Performance and Fluorescence Detection of Ionic Liquid [MBPy]Tf₂N^†

OUYANG Qiaofeng^1,², ZHENG Lanlan^1,⁴, CAO Hong^2,^*(), ZHANG Xin¹, LI Chun³, SHEN Jiao², CHEN Liting², LIU Jin²

1. School of Chemistry and Chemical Engineering, Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China
2. College of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, China
3. School of Life Science, Beijing Institute of Technology, Beijing 100081, China
4. Kashgar University, Kashi 844006, China

Received:2015-03-26 Online:2015-10-10 Published:2015-09-14
Contact: CAO Hong E-mail:chyf_ch@126.com
Supported by:
† Supported by the National Natural Science Foundation of China(Nos.21146012, 21266029), the Science and Technology Foundation of Ministry of Education, China(No.209146) and the Doctoral Foundation Project of Xinjiang Production and Construction Corps of China(No.2009JC13)

Abstract

Abstract:

The detection method of hydrophobic ionic liquid N-methyl-N-butyl pyrrolidinium bis[(trifluoro-methyl)sulfonyl]imide([MBPy]Tf₂N) was established by means of fluorescence spectrum and applied for the analysis of [MBPy]Tf₂N from glycyrrhizin biological catalysis system containing ionic liquid. The effects of solvent, ethanol-water mixture solvent and pH on fluorescence spectrum were explored. Spectral features of [MBPy]Tf₂N, the maximum absorption wavelength at 186 nm, were apparently cannot detect [MBPy]Tf₂N by common UV method. The maximum excitation wavelength of [MBPy]Tf₂N is at 228 nm and the maximum emission wavelength of it is at 340 nm, which can well againsted photobleaching and the fluorescence quantum yield was 0.067 in water. The fluorescence intensity increased in ethanol-water mixture solvent and changed much in alkaline medium. The fluorescence detection method for [MBPy]Tf₂N had a wide linear range over [MBPy]Tf₂N concentration from 5.00 to 1.25×10³μg/mL with a detection limit of 1.00 μg/mL(S/N=3). The spiked recoveries were from 97.4% to 107.4%(RSD=4.6%) in glycyrrhizin biological catalysis system.

Key words: Hydrophobic ionic liquid, N-Methyl-N-butyl pyrrolidinium bis[(trifluoromethyl)sulfonyl]imide([MBPy]Tf2N), Spectral characterization, Fluorescence detection method, Biological catalysis system

CLC Number:

O657.3

TrendMD:

OUYANG Qiaofeng, ZHENG Lanlan, CAO Hong, ZHANG Xin, LI Chun, SHEN Jiao, CHEN Liting, LIU Jin. Spectral Performance and Fluorescence Detection of Ionic Liquid [MBPy]Tf₂N^†[J]. Chem. J. Chinese Universities, 2015, 36(10): 1906.

Figures/Tables 7

Fig.1 UV absorption spectra of ionic liquid [MBPy]Tf2N in acetonitrilec/(μg·mL-1): a—g. 0, 50.05, 100.10, 150.15,

Fig.2 Emission spectra of [MBPy]Tf2N in ethanol(a), water(b) and dichloromethane(c)

Fig.3 Emission spectra of [MBPy]Tf2N and relative linearities(insets) in ethanol(A), water(B) and dichloromethane(C)

Fig.4 Photobleaching properties of [MBPy]Tf2N in water(A) Time-based fluorescence steady-state measurements of [MBPy]Tf2N in water; (B) emission spectra of [MBPy]Tf2N before(a) and after(b) photobleaching in water.

Fig.5 Effect of ethanol content on [MBPy]Tf2N fluorescenceInset is the [MBPy]Tf2N fluorescence vs. ethanol content of 80%—100%.

Fig.6 Effect of pH on [MBPy]Tf2N fluorescence

Table 1 Recoveries of [MBPy]Tf2N in bioreaction liquid

Sample	Original/(μg·mL^-1)	Spiked/(μg·mL^-1)	Found/(μg·mL^-1)	Recovery(%)	RSD(%)(n=3)
1	126.05	50.02	179.77	107.4	4.6
2	126.05	100.04	223.49	98.81	3.6
3	163.09	150.06	314.05	100.6	2.2

References 29

[1]	Rong J. F., Su Z. M., Zhang T. Z., Lin T., Chen Q. M., Cai Z. X., Chi Y. W., Chinese J. Analy. Chem. E, 2009, 37(zl), 31
	(荣杰峰, 苏志明, 张甜真, 林涛, 陈清梅, 蔡志雄, 池毓务. 分析化学,2009, 37(zl), 31)
[2]	Jia X. D., Han S. Y., Duan H. F., Lin Y. J., Cao J. G., Liang D. P., Wu M. C., Chem. Res. Chinese Universities, 2013, 29(1), 82—86
[3]	Yan R., Shao M. Y., Liang Z. F., Zhang H. Q., Yu A. M., Chem. Res. Chinese Universities, 2013, 29(2), 218—222
[4]	Simon R., Kuhnel., Balducci A., J. Phys. Chem. C, 2014, 118, 5742—5748
[5]	Shao B. B., Shi L., Meng X., Ind. Eng. Chem. Res., 2014, 53, 6655—6663
[6]	Zheng L. L., Cao H., Tang M. X., Ouyang Q. F., Zhang X., Journal of Instrumental Analysis, 2014, 33(7), 815—819
	(郑兰兰, 曹红, 唐明翔, 欧阳巧凤, 张馨. 分析测试学报,2014, 33(7), 815—819)
[7]	Faria R.A., Ponte M. N. D., Bogel-Lukasik E.,Fluid Phase Equilibria, 2014, (385), 1—9
[8]	Pang N., Gu S. S., Wang J., Bioresource Technology, 2013, 139, 337—342
[9]	Yang M. Y., Wu H., Lian Y., Li X. F., Ren Y., Lai F. R., Zhao G. L., Microbial Cell Factories, 2014, 13, 143—153
[10]	Hou X. D., Lou W. Y., Yan L. Q ., Zong M. H., Chem. J. Chinese Universities, 2012, 33(6), 1245—1251
	(侯雪丹, 娄文勇, 颜丽强, 宗敏华. 高等学校化学学报,2012, 33(6), 1245—1251)
[11]	Chen J. Y., Liu G. Y., Huang S., Tong Y. B., Li C., Chinese Journal of Bioprocess Engineering, 2011, 9(5), 17—21
	(陈金燕, 刘桂艳, 黄申, 童延斌, 李春. 生物加工过程,2011, 9(5), 17—21)
[12]	Cao H., Ye H., Li C., Zheng L. L., Li Y., Ouyang Q. F., Process Biochemistry, 2014, 49(5), 791—796
[13]	Cao H., Sun Q., Li C., Li K. X., Li J., Chem. J. Chinese Universities, 2013, 34(8), 1873—1879
	(曹红, 孙倩, 李春, 李开雄, 李军. 高等学校化学学报,2013, 34(8), 1873—1879
[14]	Cao H., Sun Q., Duan H. Y., Ye H., Chen S. Y., Liu G. Y., Transactions of Beijing Institute of Technology, 2011, 31(6), 732—736
	(曹红, 孙倩, 段海燕, 叶海, 陈思羽, 刘桂艳. 北京理工大学学报,2011, 31(6), 732—736)
[15]	Li Y., Cao H., Ouyang Q. F., Li C., Zheng L. L., Zhang X., Chem. J. Chinese Universities, 2014, 35(5), 1057—1062
	(李扬, 曹红, 欧阳巧凤, 李春, 郑兰兰, 张馨. 高等学校化学学报,2014, 35(5), 1057—1062)
[16]	Zhang R. Q., Yu H., Sun X. J., Chinese Chemical Letters, 2013, 24(6), 503—505
[17]	Huang X., Yu H., Dong Y J., Chinese Chemical Letters, 2012, 23(7), 843—846
[18]	Meng L. M., Yu H., Liu Y. Z., Chromatographia, 2011, 73(3), 367—371
[19]	Ranieri G., Hallett J. P., Welton T., Ind. Eng. Chem. Res., 2008, 47(3), 638—644
[20]	Lahiri A., Abedin S. Z. E., Endres F., J. Phys. Chem. C, 2012, 116, 17739—17745
[21]	Anthony K. B., Rico E. D. S., Sheila N. B., Mccleskey T. M., Gary A. B., Green Chem., 2007, 9, 449—454
[22]	Chen G.Z., Fluorescence Analysis, Science Press, Beijing, 1990, 75—92
	(陈国珍. 荧光分析法, 北京: 科学出版社, 1990, 75—92)
[23]	Marwani H.M.,J. Fluoresc., 2013, (23), 251—257
[24]	de Castro C. S., de Melo J. S. S., Fernandez-Lodeiro A., Nunez C., Lodeiro C., Inorg. Chem. Commun., 2014, 47, 27—32
[25]	Liang H.J., UV Spectroscopy Study of Ionic Liquids in the Solution Set of Clusters, Henan Normal University, Xinxiang, 2007
	(梁慧君. UV谱学研究离子液体在溶液中的簇集, 新乡: 河南师范大学, 2007)
[26]	Gong Z., Li X. Y., Li Z.R., Chem. J. Chinese Universities, 2004, 25(3),539—542
	(龚珍, 李象远, 李泽荣. 高等学校化学学报,2004, 25(3), 539—542)
[27]	Song W. J., Zhao C. X., Mu S. Y., Pan X. L., Zhang D. Y., Al-Misnedd F. A., Mortuza M. G., Colloids and Surfaces B: Biointerfaces, 2015, 128, 115—118
[28]	Xu J.G., Wang Z. B., Fluorescence Analysis, Science Press, Beijing, 2006, 50—52
	(许金钩, 王尊本. 荧光分析法, 北京: 科学出版社, 2006, 50—52)
[29]	Liu Y., Yu Y. M., Li H., Li J. S., Spectroscopy and Spectral Analysis, 2011, 31(11), 2981—2986
	(刘颖, 余燕敏, 李慧, 李金淑. 光谱学与光谱分析,2011, 31(11), 2981—2986)

Spectral Performance and Fluorescence Detection of Ionic Liquid [MBPy]Tf₂N^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 29

Related Articles 1

Recommended Articles

Metrics

Comments