Studies on the Atomization Mechanism of Elements on the Graphite Probe Surface in the Graphite Furnace——The Atomization Mechanism of Cadmium and Aluminium

Abstract

Abstract: The atomization mechinism of cadmium and aluminium on the graphite probe surface in the graphite furnace is studied. The result shows that the atomization of cadmium and aluminium on the graphite probe surface originates from the thermolysis of their monooxides. The appearance temperature of Cd and Al is identical with the thermolysis temperature of their oxides respectively. The active energy of atomization is related to the bond energy of M-O of their oxide.

Key words: Atomization, Graphite probe, Cadmium, Aluminium

TrendMD:

Deng Bo, Luo Yanfei. Studies on the Atomization Mechanism of Elements on the Graphite Probe Surface in the Graphite Furnace——The Atomization Mechanism of Cadmium and Aluminium[J]. Chem. J. Chinese Universities, 1990, 11(7): 780.

[1]	TAN Yan, YU Shen, LYU Jiamin, LIU Zhan, SUN Minghui, CHEN Lihua, SU Baolian. Efficient Preparation of Mesoporous γ-Al₂O₃ Microspheres and Performance of Pd-loaded Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220133.
[2]	WANG Lijun, LI Xin, HONG Song, ZHAN Xinyu, WANG Di, HAO Leiduan, SUN Zhenyu. Efficient Electrocatalytic CO₂ Reduction to CO by Tuning CdO-Carbon Black Interface [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220317.
[3]	LI Min, ZHAO Chun, FENG Qinzhong, FENG Jian, MENG Xiaojing. Experimental and DFT Studies on the Adsorption of Cd（II） Ions from Aqueous Solutions by Nanofiber Modified Thiourea Groups [J]. Chem. J. Chinese Universities, 2021, 42(12): 3680.
[4]	XU Zhongxuan,HUANG Lina,DENG Yuhua,MENG Qin. Syntheses, Structures and Properties of Homochiral Metal-organic Frameworks with Helices and Trinuclear Cluster Units Based on Semirigid Proline Derivatives^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 873.
[5]	SONG Wei, WANG Liqun, ZENG Shuangli, WANG Li, FAN Yong, XU Jianing. In situ Hydrothermal Synthesis, Crystal Structure and Fluorescence Properties of Two Cadmium Coordination Polymers^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1406.
[6]	HUANG Jian, LIU Zhigang, FAN Ruiqing, DONG Yuwei, ZHANG Huijie, WANG Yulei, YANG Yulin. Synthesis, Characterization and Blue-emission of Cd(Ⅱ)Coordination Polymers with μ-Chlorine-Bridging One-dimensional Chain Structures^† [J]. Chem. J. Chinese Universities, 2015, 36(3): 411.
[7]	LUO Jinyuan, CHEN Linlin, WANG Yi, LI Hong. Fabrication and Performance of a Novel Visible Light-driven Fuel Cell Based on Photocatalytic Oxidation of Uric Acid by CdS Nanoparticles and Electrocatalytic Reduction of Oxygen by a Copper(Ⅱ) Complex^† [J]. Chem. J. Chinese Universities, 2015, 36(12): 2468.
[8]	QU Yang, ZHOU Wei, REN Zhiyu, PAN Kai, JIANG Le, FU Honggang. Controllable Preparation of CdTiO₃ Nanorods and Their Photocatalytic Properties for Hydrogen Production^† [J]. Chem. J. Chinese Universities, 2014, 35(5): 995.
[9]	ZHANG Ling-Yun, YANG Yu-Lin, FAN Rui-Qing, ZHANG Yan-Jiao, WANG Ping, LI Liang. Performances of Dye-sensitized Solar Cell Based on ZnO Photoanode Sensitized with Cadmium Complexes Cd(phen)₂(NO₃)(NO₂) [J]. Chem. J. Chinese Universities, 2013, 34(6): 1470.
[10]	MA Dong-Dong, LIN Ping-Ping, CHEN Li-Li, WANG Yu-Hua, HE Dan-Dan, CHEN Wan-Ling, ZHANG Tian-Tian, CHEN Kui-Zhi, PENG Yi-Ru. Synthesis of Poly(ethylene glycol)-poly(L-lysine) Diblock Copolymer Incorporating Tetra-(p-sulfoazophenyl-4-aminosulfonyl)phthalocyanine Chloride Aluminum(Ⅲ) Polyion Nanoparticles and Its in vitro Photodynamic Therapy Efficacy [J]. Chem. J. Chinese Universities, 2012, 33(07): 1456.
[11]	. Synthesis, Structures and Density of State of Oxalate-bridged Dinuclear Cd(Ⅱ) Complex: [Cd2(phen)2ox(NO3)2 (H2O)2] [J]. Chem. J. Chinese Universities, 2011, 32(6): 1250.
[12]	WANG Yi-Lin*, HUANG Wu, WANG Rong-Fang, ZHOU Li-Ya. Synthesis of Highly Emissive, Color\\|tunable CdTe Quantum Dots in Aqueous Solution [J]. Chem. J. Chinese Universities, 2011, 32(12): 2727.
[13]	FANG Cai-Wang, HUANG Qing-Yu, LING Xue-Ping, KE Cai-Huan, HUANG He-Qing. Stress Proteins of Gill Tissue in Patinopecten yessoensis Exposed to Cadmium Salt [J]. Chem. J. Chinese Universities, 2010, 31(3): 507.
[14]	LI Guo-Chen , WANG Yan-Hong*, WU Ren-An, WANG Shi-Cheng. MALDI-TOF-MS for Lipidomics Analysis——Potential Biomarker for Cadmium Effect on Crucian Carp(Carassius auratus) [J]. Chem. J. Chinese Universities, 2010, 31(2): 269.
[15]	HUANG Lin^1,2, CHEN Dong-Shi¹, YAN Li¹, FANG Cai-Wang^1,3, HUANG He-Qing^1,2,3. Differential Proteins of Sub-buccal Ganglions Selected and Identified with Proteomic Techniques in Aplysia* Under the Stress Condition of Cadmium Chloride [J]. Chem. J. Chinese Universities, 2009, 30(2): 314.

Studies on the Atomization Mechanism of Elements on the Graphite Probe Surface in the Graphite Furnace——The Atomization Mechanism of Cadmium and Aluminium

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments