Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (7): 762.

• Articles • Previous Articles     Next Articles

Synthesis of New Ferrocene Derivatives Containing α,β-Unsaturated Ketone Group

Zhang Chengru, Yin Yongjun, Zhou Yaokun, Wang Liufang   

  1. Department of Chemistry, Lanzhou University, Lanzhou
  • Received:1989-01-26 Online:1990-07-24 Published:1990-07-24

Abstract: Anew method is given for the synthesis of 4-ferrocenyl-3-pentene-2-one, which involves the condensation of ferrocene with acetylacetone in concentrated sulfuric acid at -5℃. The acylation reactions of this compound is investigated, and four new derivatives are prepared. All of these compounds are identified by 1H NMR, IRand elemental analysis.

Key words: Ferrocenyl α,β-unsaturated ketone, Synthesis, Acylation reaction

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