Studies on Selective Oxidation of α,β-Unsaturated Alcohols——The Synthesis of Two New Types of Polymer Supported Oxidizing Reagents and Their Excellent Selectivity

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (7): 759.

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Studies on Selective Oxidation of α,β-Unsaturated Alcohols——The Synthesis of Two New Types of Polymer Supported Oxidizing Reagents and Their Excellent Selectivity

Yang Hulrong¹, Li Bina¹, Lu Qiansheng²

1. Department of Chemical Engineering, Guangdong Institute of Technology, Guangzhou;
2. Department of Chemistry, South China Normal University, Guangzhou

Received:1989-01-08 Online:1990-07-24 Published:1990-07-24

Abstract

Abstract: Two new types of polymer supported oxidizing reagents——dichromic acid type tertiaryamine resin and dichromic acid type quaternary ammonium resin were synthesized by using jel tertiary amine resin and jel quaternary ammonium resin as the supports. These two new types of polymer supported oxidizing reagents can successfully oxidate the α, β-unsaturated alcohols into the corresponding α,β-unsaturated aldehydes, but can not oxidate the saturated alcohols under the similar condition, which exhibits excellent selectivity.

Key words: Polymer supported oxidizing reagent, α,β-Unsaturated alcohols, Selective oxidation, Synthesis

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Yang Hulrong, Li Bina, Lu Qiansheng. Studies on Selective Oxidation of α,β-Unsaturated Alcohols——The Synthesis of Two New Types of Polymer Supported Oxidizing Reagents and Their Excellent Selectivity[J]. Chem. J. Chinese Universities, 1990, 11(7): 759.

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Studies on Selective Oxidation of α,β-Unsaturated Alcohols——The Synthesis of Two New Types of Polymer Supported Oxidizing Reagents and Their Excellent Selectivity

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