Synthesis and Characterization of Iron-Sulfur and Cobalt-Carbon Mixed Cluster Complexes μ-[(CO)6Co2PhC2S](μ-RS)Fe2(CO)6

Abstract

Abstract: It was shown that the single Fe-Scluster core complexes of (μ-PhC≡CS) (μ-RS)-Fe₂(CO)₆ 1 could undergo a complexation reaction with Co₂(CO)₈ in Et₂O at room temperature, giving the Fe-Sand Co-C double cluster core complexes of μ-[(CO)₆Co₂PhC₂S] (μ-RS)Fe₂(CO)₆ 2. Besides the structures of complexes 2 were characterized, the bond: type between Rand bridging sulfur atom and the influence of steric hindrance on the complexation reaction were also discussed.

Key words: Fe-S complex, Co-C complex, Double cluster core, Synthesis, Characterization

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Song Licheng, Mbiyangandu Kadiata, Wang Jitao . Synthesis and Characterization of Iron-Sulfur and Cobalt-Carbon Mixed Cluster Complexes μ-[(CO)₆Co₂PhC₂S](μ-RS)Fe₂(CO)₆[J]. Chem. J. Chinese Universities, 1990, 11(5): 481.

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Synthesis and Characterization of Iron-Sulfur and Cobalt-Carbon Mixed Cluster Complexes μ-[(CO)₆Co₂PhC₂S](μ-RS)Fe₂(CO)₆

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