The Crystal Structure of the Product from TNT with α,β-Unsaturated Aldehyde

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (3): 305.

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The Crystal Structure of the Product from TNT with α,β-Unsaturated Aldehyde

Chen Boren, Feng Zengguo, Liu Zuocai, Fan Guangyu, Cui Xiushan

Department of Chemical Engineering, Beijing Institute of Technology, Beijing

Received:1988-11-30 Online:1990-03-24 Published:1990-03-24

Abstract

Abstract: 3-Phenyl-5,7-dinitroquinoline-N-oxide is synthesized from 2,4,6-trinitrotoluene with cin-namaldehyde and its crystal structure has been determined by single crystal X-ray diffraction. The single crystal belongs to a triclinic system, P1 space group, a = 6. 637(3) Å, b = 7. 646(3) Å, c=13. 823(8)Å, a=75.81(4)% 3=77.63(4)° ,γ=88. 38(4)°,V = 666. 5(5) Å³. Z = 2. Least-square refinement has led to a final Rvalue of 0.045.

Key words: Nitro compound, Quinoline-N-oxide, Synthesis, Crystal structure

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Chen Boren, Feng Zengguo, Liu Zuocai, Fan Guangyu, Cui Xiushan . The Crystal Structure of the Product from TNT with α,β-Unsaturated Aldehyde[J]. Chem. J. Chinese Universities, 1990, 11(3): 305.

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The Crystal Structure of the Product from TNT with α,β-Unsaturated Aldehyde

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