The Syntheses and Properties of Substituted Semicarbazones and Thiosemicarbazones Containing Ferrocenyl Group

Abstract

Abstract: This paper reports twelve new substituted semicavbazones and thiosemicarbazones which contain ferrocenyl group. All of these compounds are characterized on the basis of elemental analysis, IRand ¹H NMR. Anumber of transition element (Cu, Co, Ni, Zn) complexes with thiosemicar-bazone prepared from formylferrcene and thiocarbohydrazide have been prepared and characterized. Using some of these compounds and Cu(Ⅱ) complexes, we have observed the bacteriostatic activity of them. It is shown that those compounds have significant bacteriostasis on Staphylococcus autreus, Bacillus Subtilis and Escherichia Coli.

Key words: Ferrocene, Ferrocenyl carbonyl compound, Ferrocenyl semicarbazone, Transition metal complex

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Qiu Changlong, Zhang Yuhong, Zhang Xiucheng . The Syntheses and Properties of Substituted Semicarbazones and Thiosemicarbazones Containing Ferrocenyl Group[J]. Chem. J. Chinese Universities, 1990, 11(3): 307.

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The Syntheses and Properties of Substituted Semicarbazones and Thiosemicarbazones Containing Ferrocenyl Group

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