Determination of TTP-Co Configuration,Synthesis of meso-Tetrakis-(3,4-methylenedioxyphenyl)porphyrin and Spcctrophotometric Study of Its Color Reaction with Cadmium

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (11): 1289.

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Determination of TTP-Co Configuration,Synthesis of meso-Tetrakis-(3,4-methylenedioxyphenyl)porphyrin and Spcctrophotometric Study of Its Color Reaction with Cadmium

Huang Zexing¹, Pan Minqi¹, Zhong Weili¹, Zhou Zhengying¹, Ren Linying¹, He Shuqiong¹, Hu Shengzhi², Shi Dashuang²

1. Department of Chemistry, Huagiao University, Quanzhou, 362001;
2. Department of Chemistry, Xiamen University, Xiamen

Received:1989-05-21 Online:1990-11-24 Published:1990-11-24

Abstract

Abstract: In this paper, configuration of TTP-Co was determinated. Awater insoluble porphyrin (TMDOPP) was synthesized and its color reaction with cadmium was studied. Ahighly sensitive method for determining cadmium at ppm× 10^-3 level was established. The simple and rapid method has been succefully applied to the direct determination of trace amount of cadmium in water sample with a satisfactory result.

Key words: meso-Tetrakis-( p-methylphenyl ) porphyrin-cobalt, meso-Tetrakis-( 3,4-methylene-dioxyphenyl) porphyrin, Cadmium, Spectrophotometry

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Huang Zexing, Pan Minqi, Zhong Weili, Zhou Zhengying, Ren Linying, He Shuqiong, Hu Shengzhi, Shi Dashuang. Determination of TTP-Co Configuration,Synthesis of meso-Tetrakis-(3,4-methylenedioxyphenyl)porphyrin and Spcctrophotometric Study of Its Color Reaction with Cadmium[J]. Chem. J. Chinese Universities, 1990, 11(11): 1289.

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Determination of TTP-Co Configuration,Synthesis of meso-Tetrakis-(3,4-methylenedioxyphenyl)porphyrin and Spcctrophotometric Study of Its Color Reaction with Cadmium

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