Synthesis, Properties and Structure of Mixed Ligand Complex of Iron(Ⅲ) with 2-[(o-Hydroxybenzylidene)amino] Phenol and Pyridine

Abstract

Abstract: The mixed ligand complex of Fe(Ⅱ) with 2[(o-hydroxybenzylidene)amino] phenol and pyridine was prepared.Its structure was determined by means of four cycle diffractometer.It was found that the crystal belongs to the monoclinic system with space group C₂/c, and the unit cell parameters are:a= 10.109(4)Å.6=23.403(7)Å.c= 18.417(3)Å, β=102.20(2)°, V = 4258.8 Å³,Z=4, D_c=1.41 g/cm³,μ=7.4 cm^-1 (Mo Ka), F(000) = 1872.The process of its thermal decomposition was investigated by means of DTAand TGtechniques.

Key words: Iron, Coordination compound, Properties, Structure

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Liu Dexin, Cui Xuegui, Geng Fangdong, Li Fengling, Kong Qingchi. Synthesis, Properties and Structure of Mixed Ligand Complex of Iron(Ⅲ) with 2-[(o-Hydroxybenzylidene)amino] Phenol and Pyridine[J]. Chem. J. Chinese Universities, 1989, 10(8): 787.

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Synthesis, Properties and Structure of Mixed Ligand Complex of Iron(Ⅲ) with 2-[(o-Hydroxybenzylidene)amino] Phenol and Pyridine

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